金属盐存在下1-烯丙氧基-4-羟基苯的微波辅助Claisen重排

IF 0.9 Q4 CHEMISTRY, MULTIDISCIPLINARY

Current Microwave Chemistry Pub Date : 2021-01-06 DOI:10.2174/2213335607666210106094449

Fumiyoshi Ozaki, Y. Okada

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引用次数: 0

摘要

在金属盐的存在下进行了烯丙氧基苯与羟基的微波辅助Claisen重排。碱金属盐的存在促进了重排，因为反应底物转化为能有效吸收微波的苯氧离子。相比之下，路易斯酸与以太氧具有强配位性，并且这种结构也可以有效地吸收微波。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Microwave-assisted Claisen Rearrangement of 1-Allyloxy-4-hydroxybenzene in the Presence of Metal Salt

Microwave-assisted Claisen rearrangement of allyloxybenzene with a hydroxyl group was conducted in the presence of metal salts. The rearrangement was promoted in the presence of an alkali metal salt, because the reaction substrate was converted into a phenoxide-type ion, which can efficiently absorb microwaves. In contrast, a Lewis acid was strongly coordinated to the ethereal oxygen, and this structure could also absorb microwaves efficiently.

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Current Microwave Chemistry CHEMISTRY, MULTIDISCIPLINARY-

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