{"title":"在保加利亚首次发现osakaite矿物Zn4(OH)6(SO4)•5H2O","authors":"P. Petrov, T. Stanimirova, Svetla Stariradeva","doi":"10.52215/rev.bgs.2022.83.3.35","DOIUrl":null,"url":null,"abstract":"Osakaite, a new mineral for Bulgaria, was discovered in stalactites from the Gyudyurska mine, South Petrovitsa deposit, South Rhodope. The chemical composition determines isomorphous inclusion of Cu2+ and composition (Zn3Cu)(OH)6(SO4)•5H2O. The mineral is a product of the interaction of mine waters passing through Zn and Cu-sulfide ores. During prolonged storage in atmospheric conditions, part of the osakaite crystals were dehydrated to the formation of the minerals namuwite Zn3Cu(OH)6(SO4)•4H2O and lahnsteinite Zn3Cu(OH)6(SO4)•3H2O.","PeriodicalId":40733,"journal":{"name":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","volume":" ","pages":""},"PeriodicalIF":0.2000,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"First occurrence of the mineral osakaite Zn4(OH)6(SO4)•5H2O for Bulgaria\",\"authors\":\"P. Petrov, T. Stanimirova, Svetla Stariradeva\",\"doi\":\"10.52215/rev.bgs.2022.83.3.35\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Osakaite, a new mineral for Bulgaria, was discovered in stalactites from the Gyudyurska mine, South Petrovitsa deposit, South Rhodope. The chemical composition determines isomorphous inclusion of Cu2+ and composition (Zn3Cu)(OH)6(SO4)•5H2O. The mineral is a product of the interaction of mine waters passing through Zn and Cu-sulfide ores. During prolonged storage in atmospheric conditions, part of the osakaite crystals were dehydrated to the formation of the minerals namuwite Zn3Cu(OH)6(SO4)•4H2O and lahnsteinite Zn3Cu(OH)6(SO4)•3H2O.\",\"PeriodicalId\":40733,\"journal\":{\"name\":\"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.2000,\"publicationDate\":\"2022-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.52215/rev.bgs.2022.83.3.35\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"GEOSCIENCES, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.52215/rev.bgs.2022.83.3.35","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
First occurrence of the mineral osakaite Zn4(OH)6(SO4)•5H2O for Bulgaria
Osakaite, a new mineral for Bulgaria, was discovered in stalactites from the Gyudyurska mine, South Petrovitsa deposit, South Rhodope. The chemical composition determines isomorphous inclusion of Cu2+ and composition (Zn3Cu)(OH)6(SO4)•5H2O. The mineral is a product of the interaction of mine waters passing through Zn and Cu-sulfide ores. During prolonged storage in atmospheric conditions, part of the osakaite crystals were dehydrated to the formation of the minerals namuwite Zn3Cu(OH)6(SO4)•4H2O and lahnsteinite Zn3Cu(OH)6(SO4)•3H2O.