Can Jiang, Shuo Han, Shihong Chen, Hongfu Zhou, Xiangdong Wang
{"title":"扩链聚对苯二甲酸乙二醇酯结晶诱导的微孔发泡行为","authors":"Can Jiang, Shuo Han, Shihong Chen, Hongfu Zhou, Xiangdong Wang","doi":"10.1177/0262489320919952","DOIUrl":null,"url":null,"abstract":"The microcellular foaming of chain-extended polyethylene terephthalate (CPET) by crystallization induction method was reported in this article. The crystallization behaviors of various polyethylene terephthalate (PET) samples which were affected by the combined effect of pyromellitic dianhydride, Surlyn, and CO2 were investigated. After Surlyn was added to CPET, the crystal nucleation of various CPET samples was improved, and numerous but small spherulites were generated. Two kinds of CPET samples with the content of 0 phr and 1 phr Surlyn were foamed at various temperature by batch foaming method. Changing the saturation temperature could adjust the appearance of high-temperature melting crystals which would affect the final cellular structures in various CPET foams. With the decrease of saturation temperature, the cell size decreased while cell density increased. At the saturation temperature of 265°C and 250°C, the cell density of CPET foam with Surlyn was one magnitude larger than CPET foam without Surlyn. At the saturation temperature of 247°C, the microcellular PET foams with the cell density of 109 cells cm−3 and the cell size less than 10 µm had been developed successfully.","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"39 1","pages":"223 - 237"},"PeriodicalIF":1.3000,"publicationDate":"2020-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489320919952","citationCount":"4","resultStr":"{\"title\":\"Crystallization-induced microcellular foaming behaviors of chain-extended polyethylene terephthalate\",\"authors\":\"Can Jiang, Shuo Han, Shihong Chen, Hongfu Zhou, Xiangdong Wang\",\"doi\":\"10.1177/0262489320919952\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The microcellular foaming of chain-extended polyethylene terephthalate (CPET) by crystallization induction method was reported in this article. The crystallization behaviors of various polyethylene terephthalate (PET) samples which were affected by the combined effect of pyromellitic dianhydride, Surlyn, and CO2 were investigated. After Surlyn was added to CPET, the crystal nucleation of various CPET samples was improved, and numerous but small spherulites were generated. Two kinds of CPET samples with the content of 0 phr and 1 phr Surlyn were foamed at various temperature by batch foaming method. Changing the saturation temperature could adjust the appearance of high-temperature melting crystals which would affect the final cellular structures in various CPET foams. With the decrease of saturation temperature, the cell size decreased while cell density increased. At the saturation temperature of 265°C and 250°C, the cell density of CPET foam with Surlyn was one magnitude larger than CPET foam without Surlyn. At the saturation temperature of 247°C, the microcellular PET foams with the cell density of 109 cells cm−3 and the cell size less than 10 µm had been developed successfully.\",\"PeriodicalId\":9816,\"journal\":{\"name\":\"Cellular Polymers\",\"volume\":\"39 1\",\"pages\":\"223 - 237\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2020-04-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1177/0262489320919952\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Cellular Polymers\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1177/0262489320919952\",\"RegionNum\":4,\"RegionCategory\":\"医学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, BIOMATERIALS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cellular Polymers","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1177/0262489320919952","RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, BIOMATERIALS","Score":null,"Total":0}
Crystallization-induced microcellular foaming behaviors of chain-extended polyethylene terephthalate
The microcellular foaming of chain-extended polyethylene terephthalate (CPET) by crystallization induction method was reported in this article. The crystallization behaviors of various polyethylene terephthalate (PET) samples which were affected by the combined effect of pyromellitic dianhydride, Surlyn, and CO2 were investigated. After Surlyn was added to CPET, the crystal nucleation of various CPET samples was improved, and numerous but small spherulites were generated. Two kinds of CPET samples with the content of 0 phr and 1 phr Surlyn were foamed at various temperature by batch foaming method. Changing the saturation temperature could adjust the appearance of high-temperature melting crystals which would affect the final cellular structures in various CPET foams. With the decrease of saturation temperature, the cell size decreased while cell density increased. At the saturation temperature of 265°C and 250°C, the cell density of CPET foam with Surlyn was one magnitude larger than CPET foam without Surlyn. At the saturation temperature of 247°C, the microcellular PET foams with the cell density of 109 cells cm−3 and the cell size less than 10 µm had been developed successfully.
期刊介绍:
Cellular Polymers is concerned primarily with the science of foamed materials, the technology and state of the art for processing and fabricating, the engineering techniques and principles of the machines used to produce them economically, and their applications in varied and wide ranging uses where they are making an increasingly valuable contribution.
Potential problems for the industry are also covered, including fire performance of materials, CFC-replacement technology, recycling and environmental legislation. Reviews of technical and commercial advances in the manufacturing and application technologies are also included.
Cellular Polymers covers these and other related topics and also pays particular attention to the ways in which the science and technology of cellular polymers is being developed throughout the world.