Luis Antonio Díaz , Marta Suárez , Jose Florindo Bartolomé , Sonia Lopez-Esteban , Belén Cabal , Arnaldo Moreno , María del Carmen Bordes , Adolfo Fernández , Carlos Pecharromán , José Serafin Moya
{"title":"属于P2O5–CaO–Na2O系统的低熔融温度玻璃，用作工业陶瓷（氧化铝、氧化锆）和传统陶瓷（陶瓷石）的涂层","authors":"Luis Antonio Díaz , Marta Suárez , Jose Florindo Bartolomé , Sonia Lopez-Esteban , Belén Cabal , Arnaldo Moreno , María del Carmen Bordes , Adolfo Fernández , Carlos Pecharromán , José Serafin Moya","doi":"10.1016/j.bsecv.2023.07.003","DOIUrl":null,"url":null,"abstract":"<div><p>This article investigates the development and potential applications of low-melting point lead-free glasses. Their importance is due to strong market demands to comply with the strict international regulations against the use of lead. In this work, a preliminary study of the existing interactions of a low-melting-temperature glass belonging to the P<sub>2</sub>O<sub>5</sub>–CaO–Na<sub>2</sub>O system when it is deposited on different ceramic substrates, both traditional (porcelain stoneware) and technical (alumina and zirconia), has been carried out. The ionic diffusion through the studied interfaces, the phases present, the composition of the glassy phase and the surface morphology of the coating have been studied by Field Emission Scanning Electron Microscopy (FESEM), with coupled EDX microanalysis. The chemical resistance of the different glassy coatings obtained is also evaluated. The results showed that these new lead-free low-melting-temperature glassy coatings are chemically and mechanically compatible, and promising candidates for applications and markets in a broad range of fields.</p></div>","PeriodicalId":56330,"journal":{"name":"Boletin de la Sociedad Espanola de Ceramica y Vidrio","volume":"63 2","pages":"Pages 104-114"},"PeriodicalIF":2.7000,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0366317523000377/pdfft?md5=dbcca89f51870077ded61ad630336f23&pid=1-s2.0-S0366317523000377-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Glass with a low-melting temperature belonging to the P2O5–CaO–Na2O system, applied as a coating on technical ceramics (alumina, zirconia) and traditional ceramics (porcelain stoneware)\",\"authors\":\"Luis Antonio Díaz , Marta Suárez , Jose Florindo Bartolomé , Sonia Lopez-Esteban , Belén Cabal , Arnaldo Moreno , María del Carmen Bordes , Adolfo Fernández , Carlos Pecharromán , José Serafin Moya\",\"doi\":\"10.1016/j.bsecv.2023.07.003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This article investigates the development and potential applications of low-melting point lead-free glasses. Their importance is due to strong market demands to comply with the strict international regulations against the use of lead. In this work, a preliminary study of the existing interactions of a low-melting-temperature glass belonging to the P<sub>2</sub>O<sub>5</sub>–CaO–Na<sub>2</sub>O system when it is deposited on different ceramic substrates, both traditional (porcelain stoneware) and technical (alumina and zirconia), has been carried out. The ionic diffusion through the studied interfaces, the phases present, the composition of the glassy phase and the surface morphology of the coating have been studied by Field Emission Scanning Electron Microscopy (FESEM), with coupled EDX microanalysis. The chemical resistance of the different glassy coatings obtained is also evaluated. The results showed that these new lead-free low-melting-temperature glassy coatings are chemically and mechanically compatible, and promising candidates for applications and markets in a broad range of fields.</p></div>\",\"PeriodicalId\":56330,\"journal\":{\"name\":\"Boletin de la Sociedad Espanola de Ceramica y Vidrio\",\"volume\":\"63 2\",\"pages\":\"Pages 104-114\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S0366317523000377/pdfft?md5=dbcca89f51870077ded61ad630336f23&pid=1-s2.0-S0366317523000377-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Boletin de la Sociedad Espanola de Ceramica y Vidrio\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0366317523000377\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Boletin de la Sociedad Espanola de Ceramica y Vidrio","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0366317523000377","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Glass with a low-melting temperature belonging to the P2O5–CaO–Na2O system, applied as a coating on technical ceramics (alumina, zirconia) and traditional ceramics (porcelain stoneware)
This article investigates the development and potential applications of low-melting point lead-free glasses. Their importance is due to strong market demands to comply with the strict international regulations against the use of lead. In this work, a preliminary study of the existing interactions of a low-melting-temperature glass belonging to the P2O5–CaO–Na2O system when it is deposited on different ceramic substrates, both traditional (porcelain stoneware) and technical (alumina and zirconia), has been carried out. The ionic diffusion through the studied interfaces, the phases present, the composition of the glassy phase and the surface morphology of the coating have been studied by Field Emission Scanning Electron Microscopy (FESEM), with coupled EDX microanalysis. The chemical resistance of the different glassy coatings obtained is also evaluated. The results showed that these new lead-free low-melting-temperature glassy coatings are chemically and mechanically compatible, and promising candidates for applications and markets in a broad range of fields.
期刊介绍：
The Journal of the Spanish Ceramic and Glass Society publishes scientific articles and communications describing original research and reviews relating to ceramic materials and glasses. The main interests are on novel generic science and technology establishing the relationships between synthesis, processing microstructure and properties of materials. Papers may deal with ceramics and glasses included in any of the conventional categories: structural, functional, traditional, composites and cultural heritage. The main objective of the Journal of the Spanish Ceramic and Glass Society is to sustain a high standard research quality by means of appropriate reviewing procedures.
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