氯苯-乙腈溶液中的微波协同动力学和结构变化

SS Birajdar, JW Gaikwad, D. Suryawanshi
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引用次数: 2

摘要

在8.845 GHz微波频段,CBZ-ACN之间的分子相互作用赋予了分子的结构行为,使得在一致的二元混合物中存在单体或多聚体。用x波段微波技术在301ºK下研究了微波频率对CBZ和ACN二元溶液中C≡N(腈)分子和Cl(氯)分子间相互作用和氢键的影响。对丁腈和氯基分子之间的合作动力学和氢键进行了深入的阐述,从而利用Luzar模型和Bruggeman因子得到了静态介电常数、过量介电常数、Kirkwood相关因子。[j]。Ind. Res. 57(2), 85- 90,2022
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Microwave assisted co-operative dynamics and structural variations in chlorobenzene-acetonitrile solutions
Molecular interactions between CBZ-ACN at 8.845 GHz of microwave frequency region confer structural behavior of molecules such that either monomers or multimers are present in the agreed binary mixtures. Effect of microwave frequency on molecular interactions and hydrogen bonding between C≡N (nitrile) molecule and Cl (chlorine) molecule of CBZ and ACN binary solutions has been studied using X-band microwave technique at 301ºK. Co-operative dynamics and hydrogen bonding between nitrile and chlorine group molecules has been thoroughly explicated thereby obtaining static dielectric constant, excess permittivity, Kirkwood correlation factor using Luzar model and Bruggeman factor. Bangladesh J. Sci. Ind. Res. 57(2), 85-90, 2022
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