{"title":"氯苯-乙腈溶液中的微波协同动力学和结构变化","authors":"SS Birajdar, JW Gaikwad, D. Suryawanshi","doi":"10.3329/bjsir.v57i2.60404","DOIUrl":null,"url":null,"abstract":"Molecular interactions between CBZ-ACN at 8.845 GHz of microwave frequency region confer structural behavior of molecules such that either monomers or multimers are present in the agreed binary mixtures. Effect of microwave frequency on molecular interactions and hydrogen bonding between C≡N (nitrile) molecule and Cl (chlorine) molecule of CBZ and ACN binary solutions has been studied using X-band microwave technique at 301ºK. Co-operative dynamics and hydrogen bonding between nitrile and chlorine group molecules has been thoroughly explicated thereby obtaining static dielectric constant, excess permittivity, Kirkwood correlation factor using Luzar model and Bruggeman factor. \nBangladesh J. Sci. Ind. Res. 57(2), 85-90, 2022","PeriodicalId":8735,"journal":{"name":"Bangladesh Journal of Scientific and Industrial Research","volume":" ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Microwave assisted co-operative dynamics and structural variations in chlorobenzene-acetonitrile solutions\",\"authors\":\"SS Birajdar, JW Gaikwad, D. Suryawanshi\",\"doi\":\"10.3329/bjsir.v57i2.60404\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Molecular interactions between CBZ-ACN at 8.845 GHz of microwave frequency region confer structural behavior of molecules such that either monomers or multimers are present in the agreed binary mixtures. Effect of microwave frequency on molecular interactions and hydrogen bonding between C≡N (nitrile) molecule and Cl (chlorine) molecule of CBZ and ACN binary solutions has been studied using X-band microwave technique at 301ºK. Co-operative dynamics and hydrogen bonding between nitrile and chlorine group molecules has been thoroughly explicated thereby obtaining static dielectric constant, excess permittivity, Kirkwood correlation factor using Luzar model and Bruggeman factor. \\nBangladesh J. Sci. Ind. Res. 57(2), 85-90, 2022\",\"PeriodicalId\":8735,\"journal\":{\"name\":\"Bangladesh Journal of Scientific and Industrial Research\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-06-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bangladesh Journal of Scientific and Industrial Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3329/bjsir.v57i2.60404\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bangladesh Journal of Scientific and Industrial Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3329/bjsir.v57i2.60404","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Microwave assisted co-operative dynamics and structural variations in chlorobenzene-acetonitrile solutions
Molecular interactions between CBZ-ACN at 8.845 GHz of microwave frequency region confer structural behavior of molecules such that either monomers or multimers are present in the agreed binary mixtures. Effect of microwave frequency on molecular interactions and hydrogen bonding between C≡N (nitrile) molecule and Cl (chlorine) molecule of CBZ and ACN binary solutions has been studied using X-band microwave technique at 301ºK. Co-operative dynamics and hydrogen bonding between nitrile and chlorine group molecules has been thoroughly explicated thereby obtaining static dielectric constant, excess permittivity, Kirkwood correlation factor using Luzar model and Bruggeman factor.
Bangladesh J. Sci. Ind. Res. 57(2), 85-90, 2022