聚合物熔体中的空气夹杂物作为固有的物理发泡剂,在旋转成型中产生泡沫

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
J. Werner, Lukas Vetter, Sebastian Hertle, M. Wolf, D. Drummer
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引用次数: 2

摘要

近年来,泡沫经历了重大的经济增长,尤其是由于其轻量化的建筑潜力。本文提出了一种新的工艺变化,使真空在旋转成型中产生泡沫结构成为可能。这种新方法是基于熔体中夹持的空气作为固有的物理发泡剂。通过在冷却或凝固阶段施加负压,气泡膨胀。结晶使现有条件冻结,从而形成泡沫结构。所提出的研究考虑了不同压力以及施加真空时的温度的影响。对聚乙烯的实验结果表明,通过改变真空压力和应用温度,可以得到不同密度和不同电池特性的组件。由此产生的泡沫组件的优点是提高了单位重量比的刚度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Air inclusions in the polymer melt functioning as intrinsic physical blowing agents for the generation of foams in rotational molding
In recent years, foams have experienced a major economic uprise, not least due to their lightweight construction potential. In this article, a new process variation is presented, which enables the generation of foamed structures in rotational molding by the utilization of vacuum. The novel method is based on entrapped air in the melt as an intrinsic physical blowing agent. By applying negative pressure in the cooling or solidification phase, the air bubbles expand. The crystallization freezes the existing conditions and thus forms the foamed structure. The investigations presented consider influences by different pressures as well as the temperature at which the vacuum is applied. The results with polyethylene show that by varying the pressure as well as the application temperature of the vacuum, components with different densities and cell characteristics result. The resulting foamed components excel by an improved stiffness per unit weight ratio.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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