磷酸活化椰壳活性炭在优化条件下的水性除铅研究

D. Senarathna, Vithushana Thangarajah, K. Abeysooriya, W. Wijesundara, A. Kumari, M. S. Thilakarathna
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引用次数: 6

摘要

重金属环境污染的全球负担仍然是急需解决的最具挑战性的问题之一。铅(Pb)已被公认为一种有毒的环境污染物。本研究的主要目的是考察磷酸活化椰子椰壳活性炭对水溶液中铅(II)的吸附效率。通过粉末X射线衍射、傅立叶变换红外光谱和扫描电子显微镜结合能量色散X射线对合成的活性炭吸附Pb(II)前后进行了表征。此外,在不同浓度的Pb(II)溶液、pH水平、吸附剂用量和接触时间的条件下,测试了合成活性炭对Pb(Ⅱ)的去除效率。用原子吸收光谱法分析了水样中Pb(II)的浓度。用50mL 5mg/L的Pd(II)离子溶液和0.20g合成的活性炭获得100%的最大Pb(II)去除率。吸附数据与Freundlich吸附等温线模型拟合良好,吸附动力学与拟二阶动力学模型拟合良好(R2为0.99)。这些结果表明,合成的活性炭可以作为一种潜在的吸附剂从废水中去除铅。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Aqueous Lead Removal under Optimized Conditions Using Phosphoric Acid Activated Coconut Coir Activated Carbon
The global burden of heavy metal environmental pollution remains one of the most challenging issues to be addressed urgently. Lead (Pb) has been well recognized as a toxic environmental pollutant. The main objective of this study was to examine the adsorption efficiency of phosphoric activated coconut coir activated carbon for lead (II) removal from an aqueous solution. Synthesized activated carbon was characterized before and after the adsorption of Pb(II) by powder X-Ray diffraction, Fourier transforms infrared spectroscopy and scanning electron microscopy coupled with energy dispersive X-Ray. Furthermore, the removal efficiency of Pb(II) of synthesized activated carbon was tested with different concentrations of Pb(II) solutions, pH levels, adsorbent dosages, and contact time. Atomic absorption spectroscopy was used to analyze the Pb(II) concentrations in water samples. The maximum Pb(II) removal percentage of 100% was obtained with 50 mL of 5 mg/L Pd(II) ion solution and 0.20 g of the synthesized activated carbon. Adsorption data were well fitted with the Freundlich adsorption isotherm model, and adsorption kinetics were fitted with the pseudo-second-order kinetic model with R2 of 0.99. These results conclude that the synthesized activated carbon can be used as a potential sorbent for the removal of lead from wastewaters.
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