电导率法作为锌金属腐蚀和缓蚀过程的一种新的监测技术

Abdelmnim M. Altwaiq, Sa’ib J. Khouri, R. Abdel-Rahem, A. Alkhawaldeh
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引用次数: 3

摘要

电导法作为一种新的监测技术,成功地应用于锌金属腐蚀和缓蚀过程的监测。在不存在和存在四种不同浓度的木质素磺酸钠(1.0、5.0、10.0和20.0 mM)的情况下,用两种不同浓度(0.10和1.00 M)的锌片测量三种不同腐蚀性溶液(HCl、NaOH和NaCl)在20.0°C下的电导率。对说明这些溶液电导率变化的曲线的分析提供了关于腐蚀强度以及腐蚀抑制行为程度的定性信息。电导率测量结果表明,木质素磺酸钠在酸性介质(对于0.10和1.00M HCl)中是一种有效的缓蚀剂,在酸性介质中它转化为木质素磺酸,但在盐和碱性介质中效果较差。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Conductivity Method as a New Monitoring Technique for Corrosion and Corrosion Inhibition Processes of Zinc Metal
The electrical conductivity method was successfully applied as a new monitoring technique to monitor the corrosion and corrosion inhibition processes of zinc metal. Measurements of electrical conductivity at 20.0°C of three different corrosive solutions (HCl, NaOH, and NaCl) were performed with two different concentrations (0.10 and 1.00 M) containing zinc sheets in the absence and presence of four different concentrations of sodium lignosulfonate (1.0, 5.0, 10.0, and 20.0 mM). The analysis of curves that illustrates the changes in electrical conductivity of these solutions provides qualitative information about the strength of corrosion as well as the extent of corrosion inhibition behavior. The results obtained from electrical conductivity measurements revealed that sodium lignosulfonate was an effective corrosion inhibitor in acidic medium (for both 0.10 and 1.00 M HCl) in which it converted into lignosulfonic acid, but was less effective in salt and alkaline media.
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