二价镧系元素与重碱土金属的烷基配合物

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Reviews Pub Date : 2021-05-01 DOI:10.1070/RCR4992

D. Khristolyubov, D. Lyubov, A. Trifonov

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引用次数: 4

摘要

综述了稀土金属+2氧化态(Sm、Eu、Yb)的烷基衍生物及其含重碱土金属(Ca、Sr、Ba)的类似物的合成、结构、反应性和催化活性的研究进展。这类独特的有机金属化合物含有高活性的M-C键，包括烷基，α-硅基甲基，以及苯，二苯基甲基和三苯基甲基衍生物，其合成方面和结构特征被考虑。参考书目包括157篇参考文献。

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Alkyl complexes of divalent lanthanides and heavy alkaline earth metals

The review presents data on the synthesis, structure, reactivity, and catalytic activity of alkyl derivatives of rare earth metals in the oxidation state +2 (Sm, Eu, Yb) and their analogues containing heavy alkaline earth metals (Ca, Sr, Ba). The synthetic aspects and structural features of this unique class of organometallic compounds, which contain highly reactive M–C bonds, including alkyl, α-silylmethyl, and also benzyl, diphenylmethyl, and triphenylmethyl derivatives are considered. The bibliography includes 157 references.

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来源期刊

Russian Chemical Reviews 化学-化学综合

CiteScore

13.00

自引率

5.20%

发文量

审稿时长

6-12 weeks

期刊介绍： Russian Chemical Reviews serves as a complete translation of the esteemed monthly review journal Uspekhi Khimii, which has been a prominent figure in Russian scientific journals since its establishment in 1932. It offers comprehensive access to the advancements made by chemists from Russia and other former Soviet Union countries. Established in 1932, Russian Chemical Reviews is committed to publishing timely and significant review articles encompassing various facets of modern chemistry, including chemical physics, physical chemistry, computational and theoretical chemistry, catalysis, coordination chemistry, analytical chemistry, organic, organometallic, and organoelement chemistry, chemistry of macromolecules, applied chemistry, biochemistry, bio-organic chemistry, biomolecular chemistry, medicinal chemistry, materials chemistry, nanochemistry, nanostructures, and environmental chemistry.