Pd-Co-Ti催化剂净化轧钢热风炉烟气中Co的应用研究

Q3 Environmental Science
Jian-dong Cai, Zehui Yu, Junda He, Jian Li
{"title":"Pd-Co-Ti催化剂净化轧钢热风炉烟气中Co的应用研究","authors":"Jian-dong Cai, Zehui Yu, Junda He, Jian Li","doi":"10.13052/spee1048-5236.4048","DOIUrl":null,"url":null,"abstract":"The Pd-Co-Ti catalyst was successfully prepared by the method of impregnation-precipitation-ball milling. The structure and redox properties of Pd-Co-Ti catalyst was investigated by N22 desorption, X-ray powder diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and H22-TPR. The results show that the Pd-Co-Ti catalyst has a large specific surface area and a rich pore structure, and there are Co33O44 and anatase TiO22 crystals in the catalyst. The synergistic effect of Pd and Co improves the redox ability of Pd-Co-Ti catalyst. The catalyst is used to treat CO in the flue gas of rolling mills. It runs for 168 hours at a space velocity of 30,000 cm33/(g⋅⋅h) and a temperature of 280∘∘C, and the CO removal rate is basically maintained at more than 90%. The ratio of inlet CO content and O22 content affects the catalyst CO removal efficiency. When the ratio is greater than 0.5, the CO removal efficiency has a downward trend. The results of this study are of great significance to the practical application of CO oxidation technology.","PeriodicalId":35712,"journal":{"name":"Strategic Planning for Energy and the Environment","volume":" ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Application Research on Pd-Co-Ti Catalyst for Purifying CO in Flue Gas of Hot-blast Stove in Steel Rolling Mill\",\"authors\":\"Jian-dong Cai, Zehui Yu, Junda He, Jian Li\",\"doi\":\"10.13052/spee1048-5236.4048\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The Pd-Co-Ti catalyst was successfully prepared by the method of impregnation-precipitation-ball milling. The structure and redox properties of Pd-Co-Ti catalyst was investigated by N22 desorption, X-ray powder diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and H22-TPR. The results show that the Pd-Co-Ti catalyst has a large specific surface area and a rich pore structure, and there are Co33O44 and anatase TiO22 crystals in the catalyst. The synergistic effect of Pd and Co improves the redox ability of Pd-Co-Ti catalyst. The catalyst is used to treat CO in the flue gas of rolling mills. It runs for 168 hours at a space velocity of 30,000 cm33/(g⋅⋅h) and a temperature of 280∘∘C, and the CO removal rate is basically maintained at more than 90%. The ratio of inlet CO content and O22 content affects the catalyst CO removal efficiency. When the ratio is greater than 0.5, the CO removal efficiency has a downward trend. The results of this study are of great significance to the practical application of CO oxidation technology.\",\"PeriodicalId\":35712,\"journal\":{\"name\":\"Strategic Planning for Energy and the Environment\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-02-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Strategic Planning for Energy and the Environment\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.13052/spee1048-5236.4048\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Environmental Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Strategic Planning for Energy and the Environment","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.13052/spee1048-5236.4048","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Environmental Science","Score":null,"Total":0}
引用次数: 0

摘要

采用浸渍-沉淀-球磨法制备了钯钴钛催化剂。采用N22脱附、x射线粉末衍射(XRD)、透射电子显微镜(TEM)、x射线光电子能谱(XPS)和H22-TPR对Pd-Co-Ti催化剂的结构和氧化还原性能进行了研究。结果表明,Pd-Co-Ti催化剂具有较大的比表面积和丰富的孔隙结构,催化剂中存在Co33O44和锐钛矿TiO22晶体。Pd和Co的协同作用提高了Pd-Co- ti催化剂的氧化还原能力。该催化剂用于处理轧钢厂烟气中的一氧化碳。在30,000 cm33/(g⋅h)的空速和280°C的温度下运行168小时,CO去除率基本保持在90%以上。进口CO含量与O22含量的比值影响催化剂的CO脱除效率。当比值大于0.5时,CO去除率呈下降趋势。研究结果对CO氧化技术的实际应用具有重要意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Application Research on Pd-Co-Ti Catalyst for Purifying CO in Flue Gas of Hot-blast Stove in Steel Rolling Mill
The Pd-Co-Ti catalyst was successfully prepared by the method of impregnation-precipitation-ball milling. The structure and redox properties of Pd-Co-Ti catalyst was investigated by N22 desorption, X-ray powder diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and H22-TPR. The results show that the Pd-Co-Ti catalyst has a large specific surface area and a rich pore structure, and there are Co33O44 and anatase TiO22 crystals in the catalyst. The synergistic effect of Pd and Co improves the redox ability of Pd-Co-Ti catalyst. The catalyst is used to treat CO in the flue gas of rolling mills. It runs for 168 hours at a space velocity of 30,000 cm33/(g⋅⋅h) and a temperature of 280∘∘C, and the CO removal rate is basically maintained at more than 90%. The ratio of inlet CO content and O22 content affects the catalyst CO removal efficiency. When the ratio is greater than 0.5, the CO removal efficiency has a downward trend. The results of this study are of great significance to the practical application of CO oxidation technology.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Strategic Planning for Energy and the Environment
Strategic Planning for Energy and the Environment Environmental Science-Environmental Science (all)
CiteScore
1.50
自引率
0.00%
发文量
25
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信