I. Sh. Khusnutdinov, I.N. Goncharova, A.G. Safiulina, D.N. Safina
{"title":"异戊二烯与各类含氧化合物相互作用合成潜在燃料添加剂","authors":"I. Sh. Khusnutdinov, I.N. Goncharova, A.G. Safiulina, D.N. Safina","doi":"10.1016/j.ejpe.2022.11.002","DOIUrl":null,"url":null,"abstract":"<div><p>Unstable market of conventional fuel resources with the high fluctuation of oil prices is shifting interest towards obtaining fuels from renewable components. Unsaturated aliphatic hydrocarbons, produced in oil refineries and from renewable bioresources, present a potential feedstock for the production of oxygen-containing additives for motor fuels. In the present paper the interaction of the simplest representative of diene series – isoprene with various classes of oxygen-containing compounds: ethyl alcohol, acetic acid, acetaldehyde, produced from biomass as well, is analyzed. The possibility of synthesizing of various acetals and paraldehyde, proposed as potential high-quality fuel additives, via interaction of isoprene with ethyl alcohol and acetaldehyde, is shown. Within the first series of experiments, sufficiently high yields of products are obtained. Yield of potential oxygen containing additives to gasoline produced via interaction of isoprene with ethanol exceeds 15 %, via interaction of isoprene with acetaldehyde: potential diesel additives −40 %, gasoline additives −12.9 %.</p></div>","PeriodicalId":11625,"journal":{"name":"Egyptian Journal of Petroleum","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Synthesis of potential fuel additives via interaction of isoprene with various classes of oxygen-containing compounds\",\"authors\":\"I. Sh. Khusnutdinov, I.N. Goncharova, A.G. Safiulina, D.N. Safina\",\"doi\":\"10.1016/j.ejpe.2022.11.002\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Unstable market of conventional fuel resources with the high fluctuation of oil prices is shifting interest towards obtaining fuels from renewable components. Unsaturated aliphatic hydrocarbons, produced in oil refineries and from renewable bioresources, present a potential feedstock for the production of oxygen-containing additives for motor fuels. In the present paper the interaction of the simplest representative of diene series – isoprene with various classes of oxygen-containing compounds: ethyl alcohol, acetic acid, acetaldehyde, produced from biomass as well, is analyzed. The possibility of synthesizing of various acetals and paraldehyde, proposed as potential high-quality fuel additives, via interaction of isoprene with ethyl alcohol and acetaldehyde, is shown. Within the first series of experiments, sufficiently high yields of products are obtained. Yield of potential oxygen containing additives to gasoline produced via interaction of isoprene with ethanol exceeds 15 %, via interaction of isoprene with acetaldehyde: potential diesel additives −40 %, gasoline additives −12.9 %.</p></div>\",\"PeriodicalId\":11625,\"journal\":{\"name\":\"Egyptian Journal of Petroleum\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Egyptian Journal of Petroleum\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1110062122000691\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Earth and Planetary Sciences\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Egyptian Journal of Petroleum","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1110062122000691","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Earth and Planetary Sciences","Score":null,"Total":0}
Synthesis of potential fuel additives via interaction of isoprene with various classes of oxygen-containing compounds
Unstable market of conventional fuel resources with the high fluctuation of oil prices is shifting interest towards obtaining fuels from renewable components. Unsaturated aliphatic hydrocarbons, produced in oil refineries and from renewable bioresources, present a potential feedstock for the production of oxygen-containing additives for motor fuels. In the present paper the interaction of the simplest representative of diene series – isoprene with various classes of oxygen-containing compounds: ethyl alcohol, acetic acid, acetaldehyde, produced from biomass as well, is analyzed. The possibility of synthesizing of various acetals and paraldehyde, proposed as potential high-quality fuel additives, via interaction of isoprene with ethyl alcohol and acetaldehyde, is shown. Within the first series of experiments, sufficiently high yields of products are obtained. Yield of potential oxygen containing additives to gasoline produced via interaction of isoprene with ethanol exceeds 15 %, via interaction of isoprene with acetaldehyde: potential diesel additives −40 %, gasoline additives −12.9 %.
期刊介绍：
Egyptian Journal of Petroleum is addressed to the fields of crude oil, natural gas, energy and related subjects. Its objective is to serve as a forum for research and development covering the following areas: • Sedimentation and petroleum exploration. • Production. • Analysis and testing. • Chemistry and technology of petroleum and natural gas. • Refining and processing. • Catalysis. • Applications and petrochemicals. It also publishes original research papers and reviews in areas relating to synthetic fuels and lubricants - pollution - corrosion - alternate sources of energy - gasification, liquefaction and geology of coal - tar sands and oil shale - biomass as a source of renewable energy. To meet with these requirements the Egyptian Journal of Petroleum welcomes manuscripts and review papers reporting on the state-of-the-art in the aforementioned topics. The Egyptian Journal of Petroleum is also willing to publish the proceedings of petroleum and energy related conferences in a single volume form.
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