{"title":"无稳定剂共沉淀法合成条件对纳米磁铁矿结构和粒径的影响","authors":"Maoxue Xia, Yu Liu, N. Huang, Hongyu Zhu, J. Hao","doi":"10.1680/jsuin.22.01044","DOIUrl":null,"url":null,"abstract":"Unique properties of magnetite (Fe3O4) nanoparticles (MNPs) have promoted wide applications in various fields, but specifying and defining preparation conditions of MNPs are still challenges for the desired monodispersed size. We discussed systematically the influence of synthesis conditions on the structure and size of MNPs in co-precipitation method without stabilizer in one system. NH4OH/Fe3+ ratio, Fe3+/Fe2+ ratio, initial concentration of HCl, total concentration of iron ions, reaction temperature, aging time and washing times were investigated. The surface of magnetite crystal was easily oxidized at high NH4OH/Fe3+ ratio, and the high pH value of the reaction system can induce the large crystalline size. The hydrodynamic diameter of MNPs was efficiently controlled by the equilibrium of DLVO forces and non-DLVO forces. An appropriate initial concentration of HCl and higher reaction temperature can reduce the crystalline size due to the decelerated nucleation rate. The aging time and the total concentration of iron affected the crystalline size positively. Noticeably, pH value of MNPs dispersion in distilled water would remarkably reduce after each washing by centrifugation due to surface absorption of hydroxy group. This research provided the fundamental support for the reproducible preparation of MNPs in co-precipitation method.","PeriodicalId":22032,"journal":{"name":"Surface Innovations","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2022-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of synthesis conditions on the structure and size of magnetite nanoparticles in co-precipitation method without stabilizer in one system\",\"authors\":\"Maoxue Xia, Yu Liu, N. Huang, Hongyu Zhu, J. Hao\",\"doi\":\"10.1680/jsuin.22.01044\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Unique properties of magnetite (Fe3O4) nanoparticles (MNPs) have promoted wide applications in various fields, but specifying and defining preparation conditions of MNPs are still challenges for the desired monodispersed size. We discussed systematically the influence of synthesis conditions on the structure and size of MNPs in co-precipitation method without stabilizer in one system. NH4OH/Fe3+ ratio, Fe3+/Fe2+ ratio, initial concentration of HCl, total concentration of iron ions, reaction temperature, aging time and washing times were investigated. The surface of magnetite crystal was easily oxidized at high NH4OH/Fe3+ ratio, and the high pH value of the reaction system can induce the large crystalline size. The hydrodynamic diameter of MNPs was efficiently controlled by the equilibrium of DLVO forces and non-DLVO forces. An appropriate initial concentration of HCl and higher reaction temperature can reduce the crystalline size due to the decelerated nucleation rate. The aging time and the total concentration of iron affected the crystalline size positively. Noticeably, pH value of MNPs dispersion in distilled water would remarkably reduce after each washing by centrifugation due to surface absorption of hydroxy group. This research provided the fundamental support for the reproducible preparation of MNPs in co-precipitation method.\",\"PeriodicalId\":22032,\"journal\":{\"name\":\"Surface Innovations\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2022-09-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surface Innovations\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1680/jsuin.22.01044\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Innovations","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1680/jsuin.22.01044","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Influence of synthesis conditions on the structure and size of magnetite nanoparticles in co-precipitation method without stabilizer in one system
Unique properties of magnetite (Fe3O4) nanoparticles (MNPs) have promoted wide applications in various fields, but specifying and defining preparation conditions of MNPs are still challenges for the desired monodispersed size. We discussed systematically the influence of synthesis conditions on the structure and size of MNPs in co-precipitation method without stabilizer in one system. NH4OH/Fe3+ ratio, Fe3+/Fe2+ ratio, initial concentration of HCl, total concentration of iron ions, reaction temperature, aging time and washing times were investigated. The surface of magnetite crystal was easily oxidized at high NH4OH/Fe3+ ratio, and the high pH value of the reaction system can induce the large crystalline size. The hydrodynamic diameter of MNPs was efficiently controlled by the equilibrium of DLVO forces and non-DLVO forces. An appropriate initial concentration of HCl and higher reaction temperature can reduce the crystalline size due to the decelerated nucleation rate. The aging time and the total concentration of iron affected the crystalline size positively. Noticeably, pH value of MNPs dispersion in distilled water would remarkably reduce after each washing by centrifugation due to surface absorption of hydroxy group. This research provided the fundamental support for the reproducible preparation of MNPs in co-precipitation method.
Surface InnovationsCHEMISTRY, PHYSICALMATERIALS SCIENCE, COAT-MATERIALS SCIENCE, COATINGS & FILMS
CiteScore
5.80
自引率
22.90%
发文量
66
期刊介绍:
The material innovations on surfaces, combined with understanding and manipulation of physics and chemistry of functional surfaces and coatings, have exploded in the past decade at an incredibly rapid pace.
Superhydrophobicity, superhydrophlicity, self-cleaning, self-healing, anti-fouling, anti-bacterial, etc., have become important fundamental topics of surface science research community driven by curiosity of physics, chemistry, and biology of interaction phenomenon at surfaces and their enormous potential in practical applications. Materials having controlled-functionality surfaces and coatings are important to the manufacturing of new products for environmental control, liquid manipulation, nanotechnological advances, biomedical engineering, pharmacy, biotechnology, and many others, and are part of the most promising technological innovations of the twenty-first century.