R. Salakhov, M. Seitzhanova, D. U. Bodykov, Larissa R. Sassykova, N. Zhakirova, T. Seilkhanov
{"title":"电液对高树脂油“卡拉赞巴斯”理化特性影响的研究","authors":"R. Salakhov, M. Seitzhanova, D. U. Bodykov, Larissa R. Sassykova, N. Zhakirova, T. Seilkhanov","doi":"10.18321/ectj999","DOIUrl":null,"url":null,"abstract":"In order to change the viscosity of high-resinous oil of the “Karazhanbas” field (Kazakhstan), the effect of electrohydraulic action on it was studied. The effect of adding an organic solvent xylene on the rheological properties of oil is investigated. A comparative study of the hydrocarbon composition of oil before and after electrohydraulic impact was carried out by the method of gas chromatographymass spectrometry. Fragment composition of oil hydrocarbons before and after electrohydraulic treatment was determined by 1H and 13C NMR spectroscopy. It is shown that the conversion of heavy oil fractions to light ones begins with a five-time electrohydraulic impact. It is determined that 20‒25 electric discharge pulses are sufficient for the quantitative process of splitting hydrocarbons. It was found that the addition of xylene to high-viscosity oil leads to an increase in the conversion of hydrocarbons under electrohydraulic action. The content of paraffins and naphthalenes in high-viscosity oil is slightly reduced during electrohydraulic processing. In oil, after electrohydraulic action, a decrease in the proportion of protons of long alkyl terminal СН3-groups of hydrocarbons is observed, which indicates the process of decomposition of heavy oil fractions into light fractions.","PeriodicalId":11795,"journal":{"name":"Eurasian Chemico-Technological Journal","volume":" ","pages":""},"PeriodicalIF":0.5000,"publicationDate":"2020-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Investigation of Electrohydraulic Effect on Physicochemical Characteristics of High-Resinous Oil “Karazhanbas”\",\"authors\":\"R. Salakhov, M. Seitzhanova, D. U. Bodykov, Larissa R. Sassykova, N. Zhakirova, T. Seilkhanov\",\"doi\":\"10.18321/ectj999\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In order to change the viscosity of high-resinous oil of the “Karazhanbas” field (Kazakhstan), the effect of electrohydraulic action on it was studied. The effect of adding an organic solvent xylene on the rheological properties of oil is investigated. A comparative study of the hydrocarbon composition of oil before and after electrohydraulic impact was carried out by the method of gas chromatographymass spectrometry. Fragment composition of oil hydrocarbons before and after electrohydraulic treatment was determined by 1H and 13C NMR spectroscopy. It is shown that the conversion of heavy oil fractions to light ones begins with a five-time electrohydraulic impact. It is determined that 20‒25 electric discharge pulses are sufficient for the quantitative process of splitting hydrocarbons. It was found that the addition of xylene to high-viscosity oil leads to an increase in the conversion of hydrocarbons under electrohydraulic action. The content of paraffins and naphthalenes in high-viscosity oil is slightly reduced during electrohydraulic processing. In oil, after electrohydraulic action, a decrease in the proportion of protons of long alkyl terminal СН3-groups of hydrocarbons is observed, which indicates the process of decomposition of heavy oil fractions into light fractions.\",\"PeriodicalId\":11795,\"journal\":{\"name\":\"Eurasian Chemico-Technological Journal\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2020-12-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Eurasian Chemico-Technological Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.18321/ectj999\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Eurasian Chemico-Technological Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.18321/ectj999","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Investigation of Electrohydraulic Effect on Physicochemical Characteristics of High-Resinous Oil “Karazhanbas”
In order to change the viscosity of high-resinous oil of the “Karazhanbas” field (Kazakhstan), the effect of electrohydraulic action on it was studied. The effect of adding an organic solvent xylene on the rheological properties of oil is investigated. A comparative study of the hydrocarbon composition of oil before and after electrohydraulic impact was carried out by the method of gas chromatographymass spectrometry. Fragment composition of oil hydrocarbons before and after electrohydraulic treatment was determined by 1H and 13C NMR spectroscopy. It is shown that the conversion of heavy oil fractions to light ones begins with a five-time electrohydraulic impact. It is determined that 20‒25 electric discharge pulses are sufficient for the quantitative process of splitting hydrocarbons. It was found that the addition of xylene to high-viscosity oil leads to an increase in the conversion of hydrocarbons under electrohydraulic action. The content of paraffins and naphthalenes in high-viscosity oil is slightly reduced during electrohydraulic processing. In oil, after electrohydraulic action, a decrease in the proportion of protons of long alkyl terminal СН3-groups of hydrocarbons is observed, which indicates the process of decomposition of heavy oil fractions into light fractions.
期刊介绍:
The journal is designed for publication of experimental and theoretical investigation results in the field of chemistry and chemical technology. Among priority fields that emphasized by chemical science are as follows: advanced materials and chemical technologies, current issues of organic synthesis and chemistry of natural compounds, physical chemistry, chemical physics, electro-photo-radiative-plasma chemistry, colloids, nanotechnologies, catalysis and surface-active materials, polymers, biochemistry.