甲烷氧化二聚反应生成c2烃

D.B. Augaliev, M. Erkibaeva, A. Aidarova, S. Tungatarova, T. Baizhumanova
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引用次数: 5

摘要

由于最现代技术的不断生产和加工,世界石油储量每天都在减少。全世界的科学家都在寻找各种原料和方法,利用丰富的天然气资源来替代石化产品。在这方面,天然气作为石油化学工业的一种替代原料来源受到了极大的关注。研究了SHS法制备的新型20%La-10%Ce20%Mg-50%甘氨酸催化剂上的甲烷脱氢反应,确定了其最佳制备条件、金属的浓度和配比,以及接触时间和工艺温度对反应方向和机理的影响。介绍了甲烷氧化脱氢制C2烃过程中采用SHS法制备的20% La-10% Ce-20% Mg-50%甘氨酸催化剂的研究结果。在实验研究的基础上,发现在找到的最佳条件下,催化剂的组成在上述反应中表现出较高的活性。由此确定了反应温度对甲烷氧化转化催化剂组成的影响,选择生成乙烷和乙烯的最佳温度为T=700o С。结果表明,CH4:O2: Ar混合物在C2烃中选择性氧化的最佳条件为:T=700o С, CH4:O2=2,5:1, 5000 h-1。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
OXIDATIVE DIMERIZATION OF METHANE TO C2 HYDROCARBONS
The world's oil reserves are decreasing every day due to the continuous production and processing of the most modern technologies. Scientists all over the world are looking for various raw materials and methods to use the vast resources of natural gas as a substitute for petrochemicals. In this regard, great attention is drawn to natural gas as an alternative source of raw materials for petrochemical industries. The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction. The results of the study of 20% La-10% Ce-20% Mg-50% glycine catalyst prepared by the SHS method in the process of oxidative dehydrogenation of methane into C2 hydrocarbons are presented. On the basis of experimental studies, it was found that the composition of the catalyst exhibits high activity in the above reaction under the found optimal conditions. Thus, the influence of reaction temperature on the developed composition of catalysts for oxidative conversion of methane has been determined that the optimum temperature for the selective formation of ethane and ethylene is T=700o С. It was found that for selective oxidation of a mixture of CH4: O2 : Ar in C2 hydrocarbons the optimal conditions are: T=700o С, CH4:O2=2,5:1, 5000 h-1.
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