三嗪基羟基查尔酮纳米金属配合物的合成、表征及抗氧化性能

IF 2.4 Q2 MULTIDISCIPLINARY SCIENCES
A. Karthikeyan, J. Suresh, K. Balaji, S. Anandhakumar, A. Arun
{"title":"三嗪基羟基查尔酮纳米金属配合物的合成、表征及抗氧化性能","authors":"A. Karthikeyan, J. Suresh, K. Balaji, S. Anandhakumar, A. Arun","doi":"10.1080/23080477.2022.2074660","DOIUrl":null,"url":null,"abstract":"ABSTRACT In the present investigation, novel triazine-based chalcone ligand (1-(2,4-dihydroxyphenyl)-3-(4-((4-((4-nitrophenyl)amino)-6-phenoxy-1,3,5-triazin-2-yl)oxy)phenyl) prop-2-en-1-one) (DNPP) is synthesized and used in metal complexes synthesis which contains iron, copper, nickel, and zinc. 1H NMR and IR spectrum of DNPP confirms the formation of the product. UV-Visible spectrum shows a peak around 400–500 nm for d-d transition. SEM with EDX shows the metal complexes is in crystalline state with the size in the range of 20–50 nm. TGA analysis shows the synthesized compound is highly stable and the residue content confirms the presence of metal in the molecular structure. Antioxidant were found out to be <50 μg/ml. Graphical Abstract","PeriodicalId":53436,"journal":{"name":"Smart Science","volume":"11 1","pages":"192 - 203"},"PeriodicalIF":2.4000,"publicationDate":"2022-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Synthesis, characterization and antioxidant property of nano-scaled metal complexes of triazine based hydroxy chalcone\",\"authors\":\"A. Karthikeyan, J. Suresh, K. Balaji, S. Anandhakumar, A. Arun\",\"doi\":\"10.1080/23080477.2022.2074660\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT In the present investigation, novel triazine-based chalcone ligand (1-(2,4-dihydroxyphenyl)-3-(4-((4-((4-nitrophenyl)amino)-6-phenoxy-1,3,5-triazin-2-yl)oxy)phenyl) prop-2-en-1-one) (DNPP) is synthesized and used in metal complexes synthesis which contains iron, copper, nickel, and zinc. 1H NMR and IR spectrum of DNPP confirms the formation of the product. UV-Visible spectrum shows a peak around 400–500 nm for d-d transition. SEM with EDX shows the metal complexes is in crystalline state with the size in the range of 20–50 nm. TGA analysis shows the synthesized compound is highly stable and the residue content confirms the presence of metal in the molecular structure. Antioxidant were found out to be <50 μg/ml. Graphical Abstract\",\"PeriodicalId\":53436,\"journal\":{\"name\":\"Smart Science\",\"volume\":\"11 1\",\"pages\":\"192 - 203\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2022-05-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Smart Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/23080477.2022.2074660\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MULTIDISCIPLINARY SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Smart Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/23080477.2022.2074660","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
引用次数: 1

摘要

摘要本文合成了新型三嗪基查尔酮配体(1-(2,4-二羟基苯基)-3-(4-(4-硝基苯基)氨基)-6-苯氧基-1,3,5-三嗪-2-基氧基)苯基)丙基-2-烯-1-酮)(DNPP),并将其用于含铁、铜、镍和锌的金属配合物的合成。DNPP的1H NMR和IR光谱证实了产物的形成。紫外可见光谱显示d-d跃迁在400-500 nm附近有一个峰。EDX扫描电镜显示金属配合物呈结晶态,尺寸在20 ~ 50 nm之间。TGA分析表明,合成的化合物具有较高的稳定性,残留物含量证实了金属在分子结构中的存在。抗氧化剂含量<50 μg/ml。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis, characterization and antioxidant property of nano-scaled metal complexes of triazine based hydroxy chalcone
ABSTRACT In the present investigation, novel triazine-based chalcone ligand (1-(2,4-dihydroxyphenyl)-3-(4-((4-((4-nitrophenyl)amino)-6-phenoxy-1,3,5-triazin-2-yl)oxy)phenyl) prop-2-en-1-one) (DNPP) is synthesized and used in metal complexes synthesis which contains iron, copper, nickel, and zinc. 1H NMR and IR spectrum of DNPP confirms the formation of the product. UV-Visible spectrum shows a peak around 400–500 nm for d-d transition. SEM with EDX shows the metal complexes is in crystalline state with the size in the range of 20–50 nm. TGA analysis shows the synthesized compound is highly stable and the residue content confirms the presence of metal in the molecular structure. Antioxidant were found out to be <50 μg/ml. Graphical Abstract
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Smart Science
Smart Science Engineering-Engineering (all)
CiteScore
4.70
自引率
4.30%
发文量
21
期刊介绍: Smart Science (ISSN 2308-0477) is an international, peer-reviewed journal that publishes significant original scientific researches, and reviews and analyses of current research and science policy. We welcome submissions of high quality papers from all fields of science and from any source. Articles of an interdisciplinary nature are particularly welcomed. Smart Science aims to be among the top multidisciplinary journals covering a broad spectrum of smart topics in the fields of materials science, chemistry, physics, engineering, medicine, and biology. Smart Science is currently focusing on the topics of Smart Manufacturing (CPS, IoT and AI) for Industry 4.0, Smart Energy and Smart Chemistry and Materials. Other specific research areas covered by the journal include, but are not limited to: 1. Smart Science in the Future 2. Smart Manufacturing: -Cyber-Physical System (CPS) -Internet of Things (IoT) and Internet of Brain (IoB) -Artificial Intelligence -Smart Computing -Smart Design/Machine -Smart Sensing -Smart Information and Networks 3. Smart Energy and Thermal/Fluidic Science 4. Smart Chemistry and Materials
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信