{"title":"不同粒径铝粉对晶硅太阳能电池铝浆烧结性能的影响","authors":"Peng Zhu, Yang Lu, Xiaolei Chen","doi":"10.1155/2022/4528768","DOIUrl":null,"url":null,"abstract":"In this paper, the effects of particle size difference of aluminum (Al) powder on physical properties of Al powder and sintering properties of Al paste were investigated. For this purpose, respectively, Al powders with four mean particle sizes were used, which were obtained by two classifications using the same nitrogen atomization process. Thermal analysis results showed that the smaller the Al particle size, the lower the oxidation temperature and the higher the reaction enthalpy, indicating higher reactivity of the Al powder. Four Al powders were prepared into Al paste by the same process, and the resistances of the paste increased with the decrease of the particle size of the aluminum powder. Electrochemical capacitance-voltage profiler (ECV) and scanning electron microscope (SEM) analysis showed that the smaller the Al particle size, the thicker the back surface field (BSF) and the higher the doping concentration of BSF. It was found that the smaller size of Al powder limited the migration of silicon, which resulted in higher concentration of silicon (Si) in the Al-Si liquid phase. This leads to reaching a balance at a higher temperature between the recrystallization of silicon from the alloy liquid and the dissolution of silicon in the liquid alloy and a higher doping concentration and a higher effective BSF doping thickness. Results of the study will provide reference for further study and application of Al paste.","PeriodicalId":14195,"journal":{"name":"International Journal of Photoenergy","volume":" ","pages":""},"PeriodicalIF":2.1000,"publicationDate":"2022-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Effects of Different Particle-Sized Al Powders on Sintering Properties of Aluminum Paste in Crystalline Silicon Solar Cell\",\"authors\":\"Peng Zhu, Yang Lu, Xiaolei Chen\",\"doi\":\"10.1155/2022/4528768\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this paper, the effects of particle size difference of aluminum (Al) powder on physical properties of Al powder and sintering properties of Al paste were investigated. For this purpose, respectively, Al powders with four mean particle sizes were used, which were obtained by two classifications using the same nitrogen atomization process. Thermal analysis results showed that the smaller the Al particle size, the lower the oxidation temperature and the higher the reaction enthalpy, indicating higher reactivity of the Al powder. Four Al powders were prepared into Al paste by the same process, and the resistances of the paste increased with the decrease of the particle size of the aluminum powder. Electrochemical capacitance-voltage profiler (ECV) and scanning electron microscope (SEM) analysis showed that the smaller the Al particle size, the thicker the back surface field (BSF) and the higher the doping concentration of BSF. It was found that the smaller size of Al powder limited the migration of silicon, which resulted in higher concentration of silicon (Si) in the Al-Si liquid phase. This leads to reaching a balance at a higher temperature between the recrystallization of silicon from the alloy liquid and the dissolution of silicon in the liquid alloy and a higher doping concentration and a higher effective BSF doping thickness. Results of the study will provide reference for further study and application of Al paste.\",\"PeriodicalId\":14195,\"journal\":{\"name\":\"International Journal of Photoenergy\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2022-11-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Photoenergy\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1155/2022/4528768\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Photoenergy","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1155/2022/4528768","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Effects of Different Particle-Sized Al Powders on Sintering Properties of Aluminum Paste in Crystalline Silicon Solar Cell
In this paper, the effects of particle size difference of aluminum (Al) powder on physical properties of Al powder and sintering properties of Al paste were investigated. For this purpose, respectively, Al powders with four mean particle sizes were used, which were obtained by two classifications using the same nitrogen atomization process. Thermal analysis results showed that the smaller the Al particle size, the lower the oxidation temperature and the higher the reaction enthalpy, indicating higher reactivity of the Al powder. Four Al powders were prepared into Al paste by the same process, and the resistances of the paste increased with the decrease of the particle size of the aluminum powder. Electrochemical capacitance-voltage profiler (ECV) and scanning electron microscope (SEM) analysis showed that the smaller the Al particle size, the thicker the back surface field (BSF) and the higher the doping concentration of BSF. It was found that the smaller size of Al powder limited the migration of silicon, which resulted in higher concentration of silicon (Si) in the Al-Si liquid phase. This leads to reaching a balance at a higher temperature between the recrystallization of silicon from the alloy liquid and the dissolution of silicon in the liquid alloy and a higher doping concentration and a higher effective BSF doping thickness. Results of the study will provide reference for further study and application of Al paste.
期刊介绍:
International Journal of Photoenergy is a peer-reviewed, open access journal that publishes original research articles as well as review articles in all areas of photoenergy. The journal consolidates research activities in photochemistry and solar energy utilization into a single and unique forum for discussing and sharing knowledge.
The journal covers the following topics and applications:
- Photocatalysis
- Photostability and Toxicity of Drugs and UV-Photoprotection
- Solar Energy
- Artificial Light Harvesting Systems
- Photomedicine
- Photo Nanosystems
- Nano Tools for Solar Energy and Photochemistry
- Solar Chemistry
- Photochromism
- Organic Light-Emitting Diodes
- PV Systems
- Nano Structured Solar Cells