М.М. Voron, S.L. Polivoda, M. Fon Pruss, Ye. Matviets
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Modification of AlSi 5 Cu 4 alloy by the obtained master-alloy showed that the modifying phase Al 3 (Ti, Zr) is able to decompose and dissolve in melts of such alloys and per- forms its germinating and grain-refinement function. In this case, in the rapidly crystallized sample of the modified alloy, the solid solution based on aluminum contains only titanium and a small amount of copper, and in the crystallized – slowly con- tains both titanium and zirconium. The grain sizes of the primary solid solution based on aluminum in both samples can be estimated as the same. Titanium is also present in small amounts in iron-containing Al 5 SiFe needle-like phases. Zirconium is found mostly in eutectic zones, which contain both silicon and copper-enriched zones. Wider and uniform zones of eutectic are observed in the sample, crystallized with slow speed. It is determined that large particles of the modifying phase during the staying in a melt can be partially dissolved, giving part of the titanium and simultaneously react with silicon, forming more refractory intermetallic particles Al 4 (Ti, Zr) 3 Si 5 . The obtained data indicates the potential suitability and simultaneous need to grind the structure of such master alloys.","PeriodicalId":33778,"journal":{"name":"Metall i lit''e Ukrainy","volume":" ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Manufacturing and research of complex Al-12Ti-8Zr master-alloy structure and efficiency\",\"authors\":\"М.М. Voron, S.L. Polivoda, M. Fon Pruss, Ye. Matviets\",\"doi\":\"10.15407/steelcast2021.02.068\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"відміча-ються більш широкі та рівномірні зони евтектики. Визначено, що крупні за розміром частинки The paper presents a method of obtaining and further study of a complex master-alloy, based on aluminum, which contains a total 20 %wt. of modifying components – titanium and zirconium. The master-alloy was obtained under the conditions of electron beam casting technology by gradual fusion of metal components and subsequent casting in the mold under vacuum conditions. The obtained master-alloy is characterized by an inhomogeneous coarse-grained structure. Intermetallic phases Al 3 (Ti, Zr) are characterized by a tetragonal structure of the crystal lattice and occupy 50 % vol. of the resulting master-alloy. In the composition of intermetallics, zirconium replaces about 25 % of titanium. Modification of AlSi 5 Cu 4 alloy by the obtained master-alloy showed that the modifying phase Al 3 (Ti, Zr) is able to decompose and dissolve in melts of such alloys and per- forms its germinating and grain-refinement function. In this case, in the rapidly crystallized sample of the modified alloy, the solid solution based on aluminum contains only titanium and a small amount of copper, and in the crystallized – slowly con- tains both titanium and zirconium. The grain sizes of the primary solid solution based on aluminum in both samples can be estimated as the same. Titanium is also present in small amounts in iron-containing Al 5 SiFe needle-like phases. Zirconium is found mostly in eutectic zones, which contain both silicon and copper-enriched zones. Wider and uniform zones of eutectic are observed in the sample, crystallized with slow speed. It is determined that large particles of the modifying phase during the staying in a melt can be partially dissolved, giving part of the titanium and simultaneously react with silicon, forming more refractory intermetallic particles Al 4 (Ti, Zr) 3 Si 5 . 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引用次数: 0
摘要
відміча-ютьсябільшширокітарівномірнізониевтектики。Визначено, що крупні за розміром частинки本文介绍了一种以铝为基材,总重量为20%的复杂中间合金的制备方法和进一步研究方法。修饰成分-钛和锆。在电子束铸造工艺条件下,通过金属构件的逐步熔合,再在真空条件下在模具中进行铸造,获得了中间合金。得到的中间合金具有不均匀的粗晶组织。金属间相Al - 3 (Ti, Zr)具有四方晶格结构,占总合金体积的50%。在金属间化合物的组成中,锆取代了约25%的钛。用所制备的中间合金对alsi5cu4合金进行变质处理,结果表明,变质相Al 3 (Ti, Zr)能够在合金熔体中分解和溶解,并具有萌发和细化晶粒的功能。在这种情况下,在快速结晶的改性合金样品中,基于铝的固溶体只含有钛和少量的铜,而在缓慢结晶的样品中同时含有钛和锆。两种样品中铝基初生固溶体的晶粒尺寸大致相同。钛也以少量存在于含铁的Al - 5 - SiFe针状相中。锆主要存在于共晶带中,共晶带中既有硅富带,也有铜富带。在样品中观察到宽而均匀的共晶区,结晶速度慢。结果表明,在熔体中停留时,改性相的大颗粒可以部分溶解,使部分钛析出,同时与硅反应,形成更难熔的金属间颗粒Al 4 (Ti, Zr) 3 Si 5。获得的数据表明,这种中间合金的潜在适用性和同时需要磨削组织。
Manufacturing and research of complex Al-12Ti-8Zr master-alloy structure and efficiency
відміча-ються більш широкі та рівномірні зони евтектики. Визначено, що крупні за розміром частинки The paper presents a method of obtaining and further study of a complex master-alloy, based on aluminum, which contains a total 20 %wt. of modifying components – titanium and zirconium. The master-alloy was obtained under the conditions of electron beam casting technology by gradual fusion of metal components and subsequent casting in the mold under vacuum conditions. The obtained master-alloy is characterized by an inhomogeneous coarse-grained structure. Intermetallic phases Al 3 (Ti, Zr) are characterized by a tetragonal structure of the crystal lattice and occupy 50 % vol. of the resulting master-alloy. In the composition of intermetallics, zirconium replaces about 25 % of titanium. Modification of AlSi 5 Cu 4 alloy by the obtained master-alloy showed that the modifying phase Al 3 (Ti, Zr) is able to decompose and dissolve in melts of such alloys and per- forms its germinating and grain-refinement function. In this case, in the rapidly crystallized sample of the modified alloy, the solid solution based on aluminum contains only titanium and a small amount of copper, and in the crystallized – slowly con- tains both titanium and zirconium. The grain sizes of the primary solid solution based on aluminum in both samples can be estimated as the same. Titanium is also present in small amounts in iron-containing Al 5 SiFe needle-like phases. Zirconium is found mostly in eutectic zones, which contain both silicon and copper-enriched zones. Wider and uniform zones of eutectic are observed in the sample, crystallized with slow speed. It is determined that large particles of the modifying phase during the staying in a melt can be partially dissolved, giving part of the titanium and simultaneously react with silicon, forming more refractory intermetallic particles Al 4 (Ti, Zr) 3 Si 5 . The obtained data indicates the potential suitability and simultaneous need to grind the structure of such master alloys.