纳米氧化锌颗粒的制备及其对环氧树脂力学和热性能影响的研究

Kadhim M. Abed
{"title":"纳米氧化锌颗粒的制备及其对环氧树脂力学和热性能影响的研究","authors":"Kadhim M. Abed","doi":"10.32894/kujss.2019.14.4.7","DOIUrl":null,"url":null,"abstract":"Nanoparticles of zinc oxide are prepared by three different chemical methods. The first one includes mixing of zinc nitrate (hexa – H 2 O) with solution of sodium hydroxide (0.4N) at a ratio of (2:1) (sampleN1). In the second method, ammonium bicarbonate solution mixed with zinc sulfate (0.2M) at a ratio of (1:2) (sampleN2). The third method includes mixing of zinc nitrate (hexa – H 2 O) with sodium hydroxide (0.6N) at a ratio of (2:1) (sampleN3), were solution of starch added as fixing agent for nanoparticles. The nanoparticles examined by X– ray diffraction technique. in addition to transmission electronic microscope to determine the volume of nanoparticles. Composites are prepared by mixing nanoparticles of zinc oxide with epoxy resin. Mechanical properties measurement showed that the hardness value of the sample (EP+N3) was (103.38) due to Shore is better than the values of the other prepared samples (EP, EP+N2, EP+N1). Also, the composite (EP+N3) showed good compressive strength which was (163.71 MPa). The value of thermal conductivity of the mentioned composite was (6.41W m -1 0 K -1 ) which indicates good thermal properties. However, the study showed that the Epoxy resin has a good response to form important composites with zinc oxide nanoparticles.","PeriodicalId":34247,"journal":{"name":"mjl@ jm`@ krkwk ldrst l`lmy@","volume":" ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation and Study the Effect of Nano Zinc Oxide Particles Upon Some Mechanical and Thermal Properties of Epoxy Resin\",\"authors\":\"Kadhim M. Abed\",\"doi\":\"10.32894/kujss.2019.14.4.7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Nanoparticles of zinc oxide are prepared by three different chemical methods. The first one includes mixing of zinc nitrate (hexa – H 2 O) with solution of sodium hydroxide (0.4N) at a ratio of (2:1) (sampleN1). In the second method, ammonium bicarbonate solution mixed with zinc sulfate (0.2M) at a ratio of (1:2) (sampleN2). The third method includes mixing of zinc nitrate (hexa – H 2 O) with sodium hydroxide (0.6N) at a ratio of (2:1) (sampleN3), were solution of starch added as fixing agent for nanoparticles. The nanoparticles examined by X– ray diffraction technique. in addition to transmission electronic microscope to determine the volume of nanoparticles. Composites are prepared by mixing nanoparticles of zinc oxide with epoxy resin. Mechanical properties measurement showed that the hardness value of the sample (EP+N3) was (103.38) due to Shore is better than the values of the other prepared samples (EP, EP+N2, EP+N1). Also, the composite (EP+N3) showed good compressive strength which was (163.71 MPa). The value of thermal conductivity of the mentioned composite was (6.41W m -1 0 K -1 ) which indicates good thermal properties. However, the study showed that the Epoxy resin has a good response to form important composites with zinc oxide nanoparticles.\",\"PeriodicalId\":34247,\"journal\":{\"name\":\"mjl@ jm`@ krkwk ldrst l`lmy@\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-12-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"mjl@ jm`@ krkwk ldrst l`lmy@\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.32894/kujss.2019.14.4.7\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"mjl@ jm`@ krkwk ldrst l`lmy@","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.32894/kujss.2019.14.4.7","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

采用三种不同的化学方法制备氧化锌纳米颗粒。第一种方法是将硝酸锌(hexa - h2o)与氢氧化钠(0.4N)溶液以2:1的比例混合(试样)。在第二种方法中,碳酸氢铵溶液与硫酸锌(0.2M)按(1:2)的比例混合(sampleN2)。第三种方法是将硝酸锌(hexa - h2o)与氢氧化钠(0.6N)按(2:1)的比例混合(样品3),加入淀粉溶液作为纳米颗粒的固化剂。用X射线衍射技术对纳米颗粒进行了检测。另外用透射电镜来测定纳米颗粒的体积。将氧化锌纳米颗粒与环氧树脂混合制备复合材料。力学性能测试表明,EP+N3的邵氏硬度值为103.38,优于其他制备的EP、EP+N2、EP+N1样品。EP+N3复合材料的抗压强度为163.71 MPa。该复合材料的导热系数为(6.41W m -1 0 K -1),具有良好的热性能。然而,研究表明,环氧树脂与氧化锌纳米颗粒形成重要的复合材料具有良好的反应性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation and Study the Effect of Nano Zinc Oxide Particles Upon Some Mechanical and Thermal Properties of Epoxy Resin
Nanoparticles of zinc oxide are prepared by three different chemical methods. The first one includes mixing of zinc nitrate (hexa – H 2 O) with solution of sodium hydroxide (0.4N) at a ratio of (2:1) (sampleN1). In the second method, ammonium bicarbonate solution mixed with zinc sulfate (0.2M) at a ratio of (1:2) (sampleN2). The third method includes mixing of zinc nitrate (hexa – H 2 O) with sodium hydroxide (0.6N) at a ratio of (2:1) (sampleN3), were solution of starch added as fixing agent for nanoparticles. The nanoparticles examined by X– ray diffraction technique. in addition to transmission electronic microscope to determine the volume of nanoparticles. Composites are prepared by mixing nanoparticles of zinc oxide with epoxy resin. Mechanical properties measurement showed that the hardness value of the sample (EP+N3) was (103.38) due to Shore is better than the values of the other prepared samples (EP, EP+N2, EP+N1). Also, the composite (EP+N3) showed good compressive strength which was (163.71 MPa). The value of thermal conductivity of the mentioned composite was (6.41W m -1 0 K -1 ) which indicates good thermal properties. However, the study showed that the Epoxy resin has a good response to form important composites with zinc oxide nanoparticles.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
3
审稿时长
10 weeks
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信