摩尔浓度比对杆状胶束溶液通过小孔流动特性的影响

IF 1.3 4区 工程技术 Q3 MECHANICS
A. Ushida, Terumitsu Sugiyama, Taisuke Sato, Ryuichi Kayaba, T. Narumi, T. Hasegawa
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引用次数: 1

摘要

本研究研究研究了棒状胶束(表面活性剂)溶液通过内径为100µm至1.0 mm的圆形孔的流动特性。使用包含阳离子表面活性剂[油基双(2-羟乙基)甲基氯化铵;Lipothoquad O/12]和抗衡离子(水杨酸钠;NaSal)的棒状胶束溶液。摩尔浓度比在0.10至100之间变化,以改变测试流体的流变特性,使用应变控制流变仪和毛细管粘度计对其进行评估。除摩尔浓度比为0.10和0.15的胶束溶液外,所有棒状胶束溶液均表现出非牛顿粘度,其表现出与水一致的牛顿粘度。在动态粘弹性测量中,通过外推斜率1和2来计算摩尔浓度比为0.10、0.15和100以外的棒状胶束溶液的弛豫时间。对于每种情况,单独用水的实验结果与实验误差范围内的理论预测一致(从而证明了实验设置的有效性)。在由广义雷诺数排列的无量纲图中,摩尔浓度比为0.10、0.15、50和100的无量纲压降与水的实验(预测)值一致。对于其他棒状胶束溶液,无量纲压降大于水的无量纲压降。换言之,发现流变和流动特性随摩尔浓度比而变化。为了深入讨论实验结果,计算了流动电阻率,当摩尔浓度比为1.0时,流动电阻率最大。当摩尔浓度比为1.0时,压降的增加也是最大的。Weissenberg数用于总结弹性特性方面的实验结果,并且发现压降的特征性增加发生在数量级为10 0的Weissenbeerg数处,在该数量级处弹性得到强烈表达。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Molar Concentration Ratio on the Flow Properties of Rod-Like Micellar Solutions Passing through Small Orifices
The flow properties of rod-like micellar (surfactant) solutions passing through circular orifices with an inner diameter of 100 µm to 1.0 mm were investigated in this study. Rod-like micellar solutions comprising a cationic surfactant [oleyl bis(2-hydroxyethyl)methylammonium chloride; Lipothoquad O/12] and a counterion (sodium salicylate; NaSal) were used. The molar concentration ratio was varied from 0.10 to 100 to change the rheological properties of the test fluid, which were evaluated using a strain-controlled rheometer and a capillary viscometer. All the rod-like micellar solutions exhibited non-Newtonian viscosity except those with molar concentration ratios of 0.10 and 0.15, which instead exhibited Newtonian viscosity consistent with that of water. In the dynamic viscoelasticity measurements, the relaxation times of the rod-like micellar solutions with molar concentration ratios other than 0.10, 0.15, and 100 were calculated by extrapolating slopes 1 and 2. For each orifice, the experimental results with water alone agreed with theoretical predictions within the experimental errors (thereby demonstrating the validity of the experimental setup). In dimensionless graphs arranged by generalized Reynolds number, the dimensionless pressure drops for the molar concentration ratios of 0.10, 0.15, 50, and 100 agreed well with the experimental (predicted) values for water. For the other rod-like-micellar solutions, the dimensionless pressure drop was larger than that for water. In other words, the rheological and flow properties were found to change with the molar concentration ratio. To discuss the experimental results in depth, the flow resistivity was calculated and was largest for the molar concentration ratio of 1.0. The increase in pressure drop was also largest for molar concentration ratio of 1.0. The Weissenberg number was used to summarize the experimental results in terms of elastic properties, and the characteristic increase in pressure drop was found to occur at a Weissenberg number on the order of 10 0 , at which elasticity was strongly expressed.
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来源期刊
Nihon Reoroji Gakkaishi
Nihon Reoroji Gakkaishi 工程技术-高分子科学
CiteScore
1.50
自引率
61.50%
发文量
47
审稿时长
>12 weeks
期刊介绍: For the communication among the members, the journal of the Society of Rheology Japan, NIHON REOROJI GAKKAISHI (5 issues per year), was established in 1973 and it is the oldest journal on rheology in Asia. The journal contains original and review articles on rheology and related topics, information for all SRJ events, and reports of domestic/overseas meetings. Articles in Japanese as well as in English are considered for publication, not only from the members but also from the researchers outside. Papers from new emerging areas of the field are particularly welcome. The electronic version of the articles is available via the internet with an open access policy.
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