跃迁偶极相在原子阿秒瞬态吸收中的作用

IF 2.3 2区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL
Guanglu Yuan, Shicheng Jiang, Zi-wei Wang, Weijie Hua, Chao Yu, C. Jin, R. Lu
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引用次数: 6

摘要

基于一个考虑原子足够束缚电子态的多级模型,我们从理论上研究了强激光场中氦的阿秒瞬态吸收光谱中过渡偶极相(TDP)的作用。通过用B样条基集求解平稳薛定谔方程,我们首先计算了束缚态之间具有明确相位的跃迁偶极矩。使用改进的多级模型,我们揭示了如果两个或多个路径从基态填充激发态,TDP在确定光谱结构中起着重要作用。我们的具有精确TDP的多级模型通过自由去除或添加特定电子态来方便地解决原子ATA光谱结构的起源,并通过直接求解含时薛定谔方程与ATA光谱进行比较来证明这一点。希望将宏观传播进一步纳入模型将为实验ATA光谱提供深入的物理见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The role of transition dipole phase in atomic attosecond transient absorption from the multi-level model
Based on a multilevel model considering enough bound electronic states of atoms, we theoretically study the role of the transition dipole phase (TDP) in the attosecond transient absorption (ATA) spectrum of helium in intense laser fields. By solving the stationary Schrödinger equation with B-spline basis sets, we first calculate the transition dipole moments with well-defined phases between the bound states. Using the modified multilevel model, we reveal that the TDP plays an important role in determining the spectral structures if two or more paths populate the excited states from the ground state. Our multilevel model with the accurate TDP is convenient to address the origin of atomic ATA spectral structures by freely removing or adding specific electronic states and has been justified by comparing with the ATA spectra via directly solving the time-dependent Schrödinger equation. Hopefully, further incorporating macroscopic propagation into the model will provide indepth physical insights into experimental ATA spectra.
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来源期刊
Structural Dynamics-Us
Structural Dynamics-Us CHEMISTRY, PHYSICALPHYSICS, ATOMIC, MOLECU-PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
CiteScore
5.50
自引率
3.60%
发文量
24
审稿时长
16 weeks
期刊介绍: Structural Dynamics focuses on the recent developments in experimental and theoretical methods and techniques that allow a visualization of the electronic and geometric structural changes in real time of chemical, biological, and condensed-matter systems. The community of scientists and engineers working on structural dynamics in such diverse systems often use similar instrumentation and methods. The journal welcomes articles dealing with fundamental problems of electronic and structural dynamics that are tackled by new methods, such as: Time-resolved X-ray and electron diffraction and scattering, Coherent diffractive imaging, Time-resolved X-ray spectroscopies (absorption, emission, resonant inelastic scattering, etc.), Time-resolved electron energy loss spectroscopy (EELS) and electron microscopy, Time-resolved photoelectron spectroscopies (UPS, XPS, ARPES, etc.), Multidimensional spectroscopies in the infrared, the visible and the ultraviolet, Nonlinear spectroscopies in the VUV, the soft and the hard X-ray domains, Theory and computational methods and algorithms for the analysis and description of structuraldynamics and their associated experimental signals. These new methods are enabled by new instrumentation, such as: X-ray free electron lasers, which provide flux, coherence, and time resolution, New sources of ultrashort electron pulses, New sources of ultrashort vacuum ultraviolet (VUV) to hard X-ray pulses, such as high-harmonic generation (HHG) sources or plasma-based sources, New sources of ultrashort infrared and terahertz (THz) radiation, New detectors for X-rays and electrons, New sample handling and delivery schemes, New computational capabilities.
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