固体氧化物电解槽阳极与互连体接触层不均匀性的数值研究

IF 2.6 4区 工程技术 Q3 ELECTROCHEMISTRY
Fuel Cells Pub Date : 2022-09-11 DOI:10.1002/fuce.202200021
Zhen Zhang MSc, Yutian Yu PhD, Fupeng Cheng PhD, Yue Lu BSc, Chengzhi Guan PhD, Leidong Xie PhD, Jian-Qiang Wang PhD
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引用次数: 1

摘要

尽管阳极侧接触层在提高固体氧化物电解电池(SOEC)堆的性能方面发挥着至关重要的作用,但在电池制造过程中很难防止缺陷的形成。由于现场观察的困难,在本研究中,建立了二维SOEC模型来研究缺陷对电池的层流、稳态传热和电化学影响。采用有限元方法求解控制方程。评估了计算场中气体速度、电流密度和温度等参数,以确定缺陷对接触层的影响。该评估表明,缺陷周围的数值计算温度与主电池显著不同,这可能导致应力分布不均,并最终导致接触层和阳极之间的分层。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Numerical study on the inhomogeneity of the contact layer between solid oxide electrolysis cell anode and the interconnect

Although the anode-side contact layer plays a vital role in the performance improvement of solid oxide electrolysis cell (SOEC) stacks, it is hard to prevent defect formation in the process of cell manufacture. Due to the difficulty of in situ observation, in this study, a 2D SOEC model was built to investigate the defects' impacts on the cell regarding laminar fluid flow, steady-state heat transfer, and electrochemistry. The finite element method was employed to solve the governing equations. The parameters in the calculating field in terms of gas velocity, current density, and temperature were evaluated to identify the impacts of the defects on the contact layer. This evaluation showed that numerically computed temperatures around the defects substantially differ from the main cell, which can lead to stress maldistribution and ultimately result in the delamination between the contact layer and anode.

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来源期刊
Fuel Cells
Fuel Cells 工程技术-电化学
CiteScore
5.80
自引率
3.60%
发文量
31
审稿时长
3.7 months
期刊介绍: This journal is only available online from 2011 onwards. Fuel Cells — From Fundamentals to Systems publishes on all aspects of fuel cells, ranging from their molecular basis to their applications in systems such as power plants, road vehicles and power sources in portables. Fuel Cells is a platform for scientific exchange in a diverse interdisciplinary field. All related work in -chemistry- materials science- physics- chemical engineering- electrical engineering- mechanical engineering- is included. Fuel Cells—From Fundamentals to Systems has an International Editorial Board and Editorial Advisory Board, with each Editor being a renowned expert representing a key discipline in the field from either a distinguished academic institution or one of the globally leading companies. Fuel Cells—From Fundamentals to Systems is designed to meet the needs of scientists and engineers who are actively working in the field. Until now, information on materials, stack technology and system approaches has been dispersed over a number of traditional scientific journals dedicated to classical disciplines such as electrochemistry, materials science or power technology. Fuel Cells—From Fundamentals to Systems concentrates on the publication of peer-reviewed original research papers and reviews.
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