镍/光氧化还原双催化与亚硫酸盐的脱氧C-S键偶联

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2022-02-28 DOI:10.1021/acs.orglett.2c00478

Shuai Zhong, Zhiwei Zhou, Feng Zhao*, Guojiang Mao, Guo-Jun Deng, Huawen Huang*

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引用次数: 4

摘要

芳基卤化物和硫醇在不同的催化体系下都能形成C-S键。在本研究中，在无碱和无外源还原剂的条件下，通过可见光诱导的光/镍双催化作用，用户友好的亚磺酸盐被用作C-S偶联的高效磺化试剂。大量的芳基硫化产物具有高选择性和对各种官能团的高耐受性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Deoxygenative C–S Bond Coupling with Sulfinates via Nickel/Photoredox Dual Catalysis

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Deoxygenative C–S Bond Coupling with Sulfinates via Nickel/Photoredox Dual Catalysis

The C–S bond formation from aryl halides and thiols has been well established under various catalytic systems. In this work, user-friendly sulfinates have been exploited as an efficient sulfenylating reagent in the C–S couplings through visible-light-induced photo/nickel dual catalysis under base- and external reductant-free conditions. A large number of aryl sulfide products were accessed with high selectivity and high tolerance of various functionalities.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.