温度对聚砜基聚合物气体分离纤维输运特性影响的实验研究

IF 2 Q4 CHEMISTRY, PHYSICAL
K. A. Smorodin, A. A. Atlaskin, D. M. Zarubin, A. N. Petukhov, S. S. Kryuchkov, A. N. Petukhova, M. E. Atlaskina, A. N. Stepakova, A. N. Markov, I. V. Vorotyntsev
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引用次数: 0

摘要

研究了不同温度范围(258.15 ~ 293.15 K)对不同组分CO2-N2二元气体混合物中聚砜基非对称聚合物气体分离纤维输运特性的影响。在这项工作的框架内,在感兴趣的温度范围内,纯气体的渗透性、扩散系数和溶解度系数的值,以及二氧化碳- n2二元气体混合物组分的渗透性系数的值,都是使用渗透流动的气相色谱分析来确定的。在这项工作中证明,在室温下,在二元混合物中二氧化碳浓度低(高达15 mol %)的情况下,分离过程最有效。实验结果表明,在其余CO2浓度范围内,低温(273.15 K)的分离效果最好。在整个考虑的二氧化碳浓度范围内,温度的进一步降低并不能使混合物的分离过程更有效。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Experimental Determination of the Effect of Temperature on the Gas Transport Characteristics of Polymeric Gas Separation Fibers Based on Polysulfone

Experimental Determination of the Effect of Temperature on the Gas Transport Characteristics of Polymeric Gas Separation Fibers Based on Polysulfone

A study of the effect of temperature in a wide range (from 258.15 up to 293.15 K) on the gas transport characteristics of asymmetric polymeric gas separation fibers based on polysulfone for the components of a CO2–N2 binary gas mixture with various compositions is carried out. Within the framework of the work, the values of the permeability, diffusion, and solubility coefficients of pure gases in the temperature range of interest as well as the values of the permeability coefficient of the components of a CO2–N2 binary gas mixture are determined using gas chromatographic analysis of the permeate flow. It is demonstrated in this work that the process of separation the most effectively occurs at room temperature in the case of a low concentration of carbon dioxide (up to 15 mol %) in the binary mixture. It is experimentally shown that the separation process is the most effective at a low temperature (273.15 K) in the rest of the range of concentrations of CO2. Further decrease in temperature does not make the process of separation of the mixture more effective throughout the entire considered range of concentrations of carbon dioxide.

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来源期刊
CiteScore
3.10
自引率
31.20%
发文量
38
期刊介绍: The journal Membranes and Membrane Technologies publishes original research articles and reviews devoted to scientific research and technological advancements in the field of membranes and membrane technologies, including the following main topics:novel membrane materials and creation of highly efficient polymeric and inorganic membranes;hybrid membranes, nanocomposites, and nanostructured membranes;aqueous and nonaqueous filtration processes (micro-, ultra-, and nanofiltration; reverse osmosis);gas separation;electromembrane processes and fuel cells;membrane pervaporation and membrane distillation;membrane catalysis and membrane reactors;water desalination and wastewater treatment;hybrid membrane processes;membrane sensors;membrane extraction and membrane emulsification;mathematical simulation of porous structures and membrane separation processes;membrane characterization;membrane technologies in industry (energy, mineral extraction, pharmaceutics and medicine, chemistry and petroleum chemistry, food industry, and others);membranes and protection of environment (“green chemistry”).The journal has been published in Russian already for several years, English translations of the content used to be integrated in the journal Petroleum Chemistry. This journal is a split off with additional topics.
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