用过的活性炭——该怎么办?

Q4 Energy
Paliva Pub Date : 2022-03-31 DOI:10.35933/paliva.2022.01.03
K. Ciahotný
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引用次数: 0

摘要

近年来,在世界上技术先进的国家,活性炭在环境保护和其他分离过程中的应用已经大大扩大。这种有趣的吸附材料的世界产量目前每年接近100万吨,并在不断增长。活性炭的最大用途是饮用水和废水处理、废气处理、金矿开采的化学方法以及工业、制药和食品加工中的精炼过程。所使用的吸附剂需要再生,以便能够继续服务或处理它的生态,如果它的再生或再激活是不可能的。本文讨论了通过再生和再活化程序恢复使用过的吸附性能的可能性,描述了这些过程之间的区别,并讨论了恢复吸附能力的碳质吸附剂的吸附能力的评价。在吸附装置中直接对饱和吸附剂进行综合再生和用新技术替代饱和吸附剂,投资成本较低,目前已在运行实践中得到应用。与有机物一起使用的饱和吸附剂通常不处理,而是在再生/再活化装置中再生或再活化。这两种技术过去也曾在捷克共和国引进和使用过。在捷克共和国,目前有两个工业设施在运行,旨在再生活性炭饱和的有机物质。在再生/再活化吸附剂的情况下,重要的是要有一个合适的具有恢复结构的吸附剂证书,它决定了吸附剂的多孔结构的恢复程度。因此,有必要调整具有恢复多孔结构的吸附剂对捕获物质的预期吸附容量,以及随后的吸附剂交换间隔。只有这样,吸附设备才能满足整个运行过程中确定的排放限值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Used activated carbon – what to do about it?
The use of activated carbon in environmental protection and other separation processes has expanded considerably in recent years in the technologically advanced countries of the world. World production of this interesting adsorbent material is currently approaching 1 million tons per year and is growing constantly. The largest use of activated carbon is in the field of drinking and wastewater treatment, waste gas treatment, chemical methods of gold mining and refining processes in industrial, pharmaceutical and food processing. The sorbent used needs to be regenerated in order to be able to continue to serve or to dispose of it ecologically if its regeneration or reactivation is not possible. The article deals with the possibilities of the restoration of sorption properties of used by regeneration and reactivation procedures, describes the differences between these processes, and also deals with evaluation of the sorption capacities of carbonaceous sorbents with restored sorption capacity. The technologies that use integrated regeneration of the saturated adsorbent directly in the adsorption plant and technologies that replace the saturated adsorbent with new ones, which show more favorable investment costs, are currently used in the operational practice. The saturated adsorbent used with organic substances is usually not disposed of, but regenerated or reactivated in the regeneration / reactivation plant. Both of these technologies have also been introduced and operated in the Czech Republic in the past. In the Czech Republic, there are currently two industrial facilities in operation designed to regenerate activated carbon saturated with organic substances. In the case of regenerated / reactivated sorbents, it is important to have a suitable sorbent certificate with a restored structure, which determines the degree of restoration of the porous structure of the sorbent. Because of this, it is necessary to adjust the expected adsorption capacity of the sorbent with a restored porous structure for the captured substances, and subsequently also the sorbent exchange interval. Only in this way will the adsorption equipment meet the emission limits determined throughout the operation.
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来源期刊
Paliva
Paliva Earth and Planetary Sciences-Geotechnical Engineering and Engineering Geology
CiteScore
0.50
自引率
0.00%
发文量
15
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