由硫原子衍生的多种化学物质的研究~古川直一教授在杂原子化学中的足迹~

IF 1.1 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Heteroatom Chemistry Pub Date : 2019-01-28 DOI:10.1002/hc.21475

Soichi Sato

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引用次数: 1

摘要

本文总结了古川直一教授在杂原子化学领域的代表性贡献。从三价硫与有机金属试剂的反应中发展出了硫衍生物的配体偶联反应和配体交换反应。Furukawa教授还报道了通过跨环和分子间相互作用产生的大量单键和双键化合物。此外，还介绍了仅含碳配体的超配位硫化物的检测和分离，以及噻吩s -氧化物的有效合成方法及其反应活性。

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Studies on diverse chemical species derived from chalcogen atoms ~ The Footprint of Professor Naomichi Furukawa in Heteroatom Chemistry ~

This account summarizes representative contributions of Prof. Naomichi Furukawa to the field of heteroatom chemistry. Ligand-coupling reactions (LCRs) and ligand-exchange reactions (LERs) of chalcogen derivatives were developed from reactions of trivalent chalcogen species with organometallic reagents. Prof. Furukawa has also reported a large number of mono- and dicationic compounds generated via transannular and intermolecular interactions. Furthermore, the detection and isolation of hypercoordinated chalcogen species bearing only carbon ligands and an efficient method for the synthesis of thiophene S-oxides and their reactivity are described.

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来源期刊

Heteroatom Chemistry 化学-化学综合

CiteScore

1.20

自引率

0.00%

发文量

审稿时长

6 months

期刊介绍： Heteroatom Chemistry brings together a broad, interdisciplinary group of chemists who work with compounds containing main-group elements of groups 13 through 17 of the Periodic Table, and certain other related elements. The fundamental reactivity under investigation should, in all cases, be concentrated about the heteroatoms. It does not matter whether the compounds being studied are acyclic or cyclic; saturated or unsaturated; monomeric, polymeric or solid state in nature; inorganic, organic, or naturally occurring, so long as the heteroatom is playing an essential role. Computational, experimental, and combined studies are equally welcome. Subject areas include (but are by no means limited to): -Reactivity about heteroatoms for accessing new products or synthetic pathways -Unusual valency main-group element compounds and their properties -Highly strained (e.g. bridged) main-group element compounds and their properties -Photochemical or thermal cleavage of heteroatom bonds and the resulting reactivity -Uncommon and structurally interesting heteroatom-containing species (including those containing multiple bonds and catenation) -Stereochemistry of compounds due to the presence of heteroatoms -Neighboring group effects of heteroatoms on the properties of compounds -Main-group element compounds as analogues of transition metal compounds -Variations and new results from established and named reactions (including Wittig, Kabachnik–Fields, Pudovik, Arbuzov, Hirao, and Mitsunobu) -Catalysis and green syntheses enabled by heteroatoms and their chemistry -Applications of compounds where the heteroatom plays a critical role. In addition to original research articles on heteroatom chemistry, the journal welcomes focused review articles that examine the state of the art, identify emerging trends, and suggest future directions for developing fields.