电子束处理对AlCoCrFeNi高熵合金组织和性能的影响

IF 0.6 Q4 METALLURGY & METALLURGICAL ENGINEERING
V. Gromov, Y. Ivanov, S. Konovalov, K. Osintsev
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引用次数: 4

摘要

近年来,一种被称为高熵合金(HEA)的新合金体系吸引了科学家的注意[1-3]。与传统合金不同,高熵合金由五种或五种以上的主要元素组成,其百分比为5至35at.%[4-7]。高熵合金的思想是,所有元素的原子都被视为溶解物质的原子,导致晶体结构变形,并提高与成分原子半径差异相关的性质的热力学稳定性。它导致系统的高熵,以进一步制造具有独特性能的材料,这在传统的微合金技术中是不可能的[8-10]。分析综述[11-13]详细考虑了在HEA领域获得的原始结果,其中描述了HEA的微观结构、性能和热力学,考虑了其结构的建模结果,并讨论了获得多组分合金的方法的新变体。HEA研究表明,由于取代元素原子半径的差异导致晶格发生相当大的畸变,因此有可能在其中形成纳米级结构甚至非晶相[1]。目前,几乎所有类型的此类合金(结构、耐低温、耐热、耐腐蚀、具有特殊磁性和电学性能的合金)以及化合物(碳化物、氮化物、氧化物、硼化物、硅化物)都在开发中[14]。合金性能的改善可以通过用集中的能量流处理表面来实现。与传统的热处理和化学热处理方法相比,具有集中能量通量的硬化材料的主要特征是其表面层的纳米结构。这意味着表面塑性变形局部化的尺度水平降低,这导致在操作因素的影响下,表面附近的弹性应力分布更加均匀。结果,表面层中微裂纹成核导致失效的概率显著降低。这提高了强度和延展性。电子束处理是产品表面硬化最有前途和最有效的方法之一[15,16]。电子束处理提供了表面层到预定温度的超高加热速率(高达106 K/s),并由于以104–109 K/s的速度将热量转移到材料本体而对表面层进行冷却,从而形成不均匀的亚微米-纳米晶体结构相态。电子束处理对AlCoCrFeNi高熵合金组织和性能的影响
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of electron beam treatment on the structure and properties of AlCoCrFeNi high-entropy alloy
In last years, a new system of alloys known as highentropy alloys (HEA) has been attracting scientists’ attention [1–3]. Unlike traditional alloys high-entropy ones are composed of five and more main elements with a percentage from 5 to 35 at.% [4–7]. The idea of high-entropy alloys is that atoms of all elements are considered atoms of a dissolved substance, cause deformation of a crystal structure and improve thermodynamic stability of properties related to differences in atomic radii of components. It results in high entropy of a system to further manufacturing a material with unique properties, which are impossible in traditional micro-alloying techniques [8–10]. The original results obtained in the field of HEA are considered in detail in analytical reviews [11–13] where the HEA microstructure, properties, thermodynamics are described, results of modelling of their structure are considered and new variants of methods for obtaining the multi-component alloys are discussed. The HEA studies have shown that it is possible to form in them nanodimensional structures and even amorphous phases due to considerable distortions of lattice caused by difference in the atomic radii of substitution elements [1]. Present day practically all types of such alloys (structural, cryoand heat resistant, corrosion-resistant, those with special magnetic and electrical properties) as well as compounds (carbides, nitrides, oxides, borides, silicides) are being developed [14]. Improvement of alloy properties can be achieved by treating the surface with concentrated energy flows. The main feature of hardening materials with concentrated energy fluxes, in comparison with the methods of traditional thermal and chemical-thermal treatment, is the nanostructuring of their surface layers. This means a decrease in the scale level of localization of plastic deformation of the surface, which leads to a more uniform distribution of elastic stresses near it under the influence of operational factors. As a result, the probability of nucleation of microcracks in the surface layer leading to failure is significantly reduced. This increases both strength and ductility. One of the most promising and highly effective methods of surface hardening of products is electron-beam processing [15, 16]. Electron beam processing provides ultrahigh heating rates (up to 106 K/s) of the surface layer to predetermined temperatures and cooling of the surface layer due to heat removal to the bulk of the material at speeds of 104–109 K/s, resulting in the formation of non-uniform submicron nanocrystalline structural phase states. Effect of electron beam treatment on the structure and properties of AlCoCrFeNi high-entropy alloy
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来源期刊
CIS Iron and Steel Review
CIS Iron and Steel Review METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
2.50
自引率
12.50%
发文量
21
期刊介绍: “CIS Iron and Steel Review” is the only Russian metallurgical scientific-technical journal in English, publishing materials about whole spectrum of the problems, innovations and news of foreign iron and steel industry. The mission of this edition is to make foreign specialists aware about scientific and technical researches and development in iron and steel industry in the former USSR countries.
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