矿物在水中溶解度的温度依赖性。第2部分。碱土溴

IF 4.4 2区工程技术 Q2 CHEMISTRY, MULTIDISCIPLINARY

Journal of Physical and Chemical Reference Data Pub Date : 2018-01-25 DOI:10.1063/1.5010290

B. Krumgalz

{"title":"矿物在水中溶解度的温度依赖性。第2部分。碱土溴","authors":"B. Krumgalz","doi":"10.1063/1.5010290","DOIUrl":null,"url":null,"abstract":"Databases of alkaline and alkaline earth bromide solubilities in water at various temperatures were created using experimental data from publications over about the last two centuries. Statistical critical evaluation of the created databases was produced since there were enough independent data sources to justify such evaluation. The reliable experimental data were adequately described by polynomial expressions over various temperature ranges. Using the Pitzer approach for ionic activity and osmotic coefficients, the thermodynamic solubility products for the discussed bromide minerals have been calculated at various temperature intervals and also represented by polynomial expressions.","PeriodicalId":16783,"journal":{"name":"Journal of Physical and Chemical Reference Data","volume":"47 1","pages":"013101"},"PeriodicalIF":4.4000,"publicationDate":"2018-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1063/1.5010290","citationCount":"34","resultStr":"{\"title\":\"Temperature Dependence of Mineral Solubility in Water. Part 2. Alkaline and Alkaline Earth Bromides\",\"authors\":\"B. Krumgalz\",\"doi\":\"10.1063/1.5010290\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Databases of alkaline and alkaline earth bromide solubilities in water at various temperatures were created using experimental data from publications over about the last two centuries. Statistical critical evaluation of the created databases was produced since there were enough independent data sources to justify such evaluation. The reliable experimental data were adequately described by polynomial expressions over various temperature ranges. Using the Pitzer approach for ionic activity and osmotic coefficients, the thermodynamic solubility products for the discussed bromide minerals have been calculated at various temperature intervals and also represented by polynomial expressions.\",\"PeriodicalId\":16783,\"journal\":{\"name\":\"Journal of Physical and Chemical Reference Data\",\"volume\":\"47 1\",\"pages\":\"013101\"},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2018-01-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1063/1.5010290\",\"citationCount\":\"34\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Physical and Chemical Reference Data\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1063/1.5010290\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Physical and Chemical Reference Data","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1063/1.5010290","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 34

摘要

使用过去两个世纪出版的实验数据创建了不同温度下碱土溴在水中的溶解度数据库。由于有足够的独立数据来源证明这种评价是合理的，因此对所创建的数据库进行了统计批判性评价。在不同的温度范围内，用多项式表达式充分描述了可靠的实验数据。使用离子活性和渗透系数的Pitzer方法，计算了所讨论的溴化物矿物在不同温度区间的热力学溶解度产物，并用多项式表达式表示。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Temperature Dependence of Mineral Solubility in Water. Part 2. Alkaline and Alkaline Earth Bromides

Databases of alkaline and alkaline earth bromide solubilities in water at various temperatures were created using experimental data from publications over about the last two centuries. Statistical critical evaluation of the created databases was produced since there were enough independent data sources to justify such evaluation. The reliable experimental data were adequately described by polynomial expressions over various temperature ranges. Using the Pitzer approach for ionic activity and osmotic coefficients, the thermodynamic solubility products for the discussed bromide minerals have been calculated at various temperature intervals and also represented by polynomial expressions.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Physical and Chemical Reference Data 化学-化学综合

CiteScore

6.90

自引率

11.60%

发文量

审稿时长

>12 weeks

期刊介绍： The Journal of Physical and Chemical Reference Data (JPCRD) is published by AIP Publishing for the U.S. Department of Commerce National Institute of Standards and Technology (NIST). The journal provides critically evaluated physical and chemical property data, fully documented as to the original sources and the criteria used for evaluation, preferably with uncertainty analysis. Critical reviews may also be included if they document a reference database, review the data situation in a field, review reference-quality measurement techniques, or review data evaluation methods.