乙酰丙酮Vanadyl 2介导的1,3,5-三嗪在130°C甲苯溶液中的水解裂解:其轴向甲酰胺加合物的晶体结构

E. Arslan, I. Bernal, R. Lalancette
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引用次数: 0

摘要

双(乙酰丙酮酸钒)与1,3,5-三嗪的甲苯反应产生三嗪的对称三倍水解裂解,并且在晶体结构中发现这三个甲酰胺部分。其中一种生成的甲酰胺附着在钒基络合物的第六个(轴向)位置,产生剩余两种甲酰胺被困在生成的晶格中的材料。这些晶体属于空间组Pca21,Z=4,对于在100K下收集的3213个数据,最终R因子=0.030。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Vanadyl(acetylacetonate)2 mediated hydrolytic splitting of 1,3,5-triazine in a solution of toluene at 130 °C: The crystal structure of its axial formamide adduct
A toluene reaction of vanadyl bis(acetylacetonate) with 1,3,5-triazine produces a symmetrical three-fold hydrolytic cleavage of the triazine, and these three formamide moieties are found in the crystal structure. One of the resulting formamides attaches itself to the sixth (axial) position of the vanadyl complex, producing materials in which the remaining two formamides are trapped in the resulting lattice. Those crystals belong in space group Pca21, Z = 4 and the final R-factor = 0.030 for 3213 data collected at 100 K.
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