{"title":"一种新的经济友好的处理方法:复合水凝胶","authors":"N. D. Radhy, Layth S. Jasim","doi":"10.22124/CJES.2021.5006","DOIUrl":null,"url":null,"abstract":"There are many chemical indicators of drinking water pollution. These include heavy metals, radioactive materials, inorganic chemicals, organic chemicals, disinfectants, and disinfectant additives. Common methods for removing these contaminants from aqueous solutions include chemical precipitation, membrane processes, ion exchange processes, biological processes, adsorption, and chemical reactions. Each of these methods has limitations in application. Many studies have been performed on the use of graphene in filters. Graphite oxide (GO) platelets were prepared using a modified Hummers method. By employing GO platelets, GO/poly (acrylic acid – maleic acid) superabsorbent composites were synthesized by a free radical polymerization of acrylic acid and maleic acid as a monomer, using N, N -methylenebisacrylamide as cross-linker and ammonium persulfate as initiator. The well-dispersed GO platelets in the polymer networks result in a significant improvement in absorbencies in distilled water solutions. The superabsorbent nanocomposite also exhibits a superior water-retention ability compared with the control under the same conditions. GO/P(AA-MA) composite was investigated using felid emission scanning electron microscopy (FE-SEM) and Fourier transform infrared (FTIR); GO/P (AA-MA) composite is a highly effective absorbent of crystal violet (CV) and can be used to remove CV from aqueous solution. The kinetics of dye adsorption has been studied in terms of pseudo-first-order and pseudo-second-order rate expression. The results indicated that the adsorption process followed two models and demonstrated that intraparticle diffusion plays a significant role in the adsorption mechanism.","PeriodicalId":9640,"journal":{"name":"caspian journal of environmental sciences","volume":"1 1","pages":"1-12"},"PeriodicalIF":0.0000,"publicationDate":"2021-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"A novel economical friendly treatment approach: Composite hydrogels\",\"authors\":\"N. D. Radhy, Layth S. Jasim\",\"doi\":\"10.22124/CJES.2021.5006\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"There are many chemical indicators of drinking water pollution. These include heavy metals, radioactive materials, inorganic chemicals, organic chemicals, disinfectants, and disinfectant additives. Common methods for removing these contaminants from aqueous solutions include chemical precipitation, membrane processes, ion exchange processes, biological processes, adsorption, and chemical reactions. Each of these methods has limitations in application. Many studies have been performed on the use of graphene in filters. Graphite oxide (GO) platelets were prepared using a modified Hummers method. By employing GO platelets, GO/poly (acrylic acid – maleic acid) superabsorbent composites were synthesized by a free radical polymerization of acrylic acid and maleic acid as a monomer, using N, N -methylenebisacrylamide as cross-linker and ammonium persulfate as initiator. The well-dispersed GO platelets in the polymer networks result in a significant improvement in absorbencies in distilled water solutions. The superabsorbent nanocomposite also exhibits a superior water-retention ability compared with the control under the same conditions. GO/P(AA-MA) composite was investigated using felid emission scanning electron microscopy (FE-SEM) and Fourier transform infrared (FTIR); GO/P (AA-MA) composite is a highly effective absorbent of crystal violet (CV) and can be used to remove CV from aqueous solution. The kinetics of dye adsorption has been studied in terms of pseudo-first-order and pseudo-second-order rate expression. The results indicated that the adsorption process followed two models and demonstrated that intraparticle diffusion plays a significant role in the adsorption mechanism.\",\"PeriodicalId\":9640,\"journal\":{\"name\":\"caspian journal of environmental sciences\",\"volume\":\"1 1\",\"pages\":\"1-12\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-09-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"caspian journal of environmental sciences\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22124/CJES.2021.5006\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Agricultural and Biological Sciences\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"caspian journal of environmental sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22124/CJES.2021.5006","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Agricultural and Biological Sciences","Score":null,"Total":0}
引用次数: 6
摘要
饮用水污染的化学指标有很多。这些包括重金属、放射性物质、无机化学品、有机化学品、消毒剂和消毒剂添加剂。从水溶液中去除这些污染物的常用方法包括化学沉淀法、膜法、离子交换法、生物法、吸附法和化学反应。每种方法在应用上都有局限性。关于石墨烯在过滤器中的应用已经进行了许多研究。采用改进的Hummers法制备氧化石墨(GO)薄片。以氧化石墨烯薄片为原料,以丙烯酸和马来酸为单体,N, N -亚甲基双丙烯酰胺为交联剂,过硫酸铵为引发剂,采用自由基聚合法制备了氧化石墨烯/聚丙烯酸-马来酸高吸水性复合材料。聚合物网络中分散良好的氧化石墨烯薄片显著提高了其在蒸馏水溶液中的吸收能力。在相同条件下,与对照相比,高吸水性纳米复合材料也表现出更好的保水能力。采用场发射扫描电镜(FE-SEM)和傅里叶变换红外(FTIR)对氧化石墨烯/聚丙烯酸甲酯(AA-MA)复合材料进行了研究;GO/P (AA-MA)复合材料是一种高效的结晶紫(CV)吸附剂,可用于去除水溶液中的CV。用拟一级和拟二级速率表达式研究了染料吸附动力学。结果表明,吸附过程遵循两种模式,并表明颗粒内扩散在吸附机理中起重要作用。
A novel economical friendly treatment approach: Composite hydrogels
There are many chemical indicators of drinking water pollution. These include heavy metals, radioactive materials, inorganic chemicals, organic chemicals, disinfectants, and disinfectant additives. Common methods for removing these contaminants from aqueous solutions include chemical precipitation, membrane processes, ion exchange processes, biological processes, adsorption, and chemical reactions. Each of these methods has limitations in application. Many studies have been performed on the use of graphene in filters. Graphite oxide (GO) platelets were prepared using a modified Hummers method. By employing GO platelets, GO/poly (acrylic acid – maleic acid) superabsorbent composites were synthesized by a free radical polymerization of acrylic acid and maleic acid as a monomer, using N, N -methylenebisacrylamide as cross-linker and ammonium persulfate as initiator. The well-dispersed GO platelets in the polymer networks result in a significant improvement in absorbencies in distilled water solutions. The superabsorbent nanocomposite also exhibits a superior water-retention ability compared with the control under the same conditions. GO/P(AA-MA) composite was investigated using felid emission scanning electron microscopy (FE-SEM) and Fourier transform infrared (FTIR); GO/P (AA-MA) composite is a highly effective absorbent of crystal violet (CV) and can be used to remove CV from aqueous solution. The kinetics of dye adsorption has been studied in terms of pseudo-first-order and pseudo-second-order rate expression. The results indicated that the adsorption process followed two models and demonstrated that intraparticle diffusion plays a significant role in the adsorption mechanism.