膨胀聚苯乙烯涂料固化过程中的应力

Loganina Vi, Kislitsyna Sn, Mazhitov Yb
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引用次数: 0

摘要

本文的目的是评估基于发泡聚苯乙烯溶液的涂层的抗裂性。根据固化时间和涂层厚度,提供了基于发泡聚苯乙烯溶液的涂层的应力状态信息。确定了聚合物涂层的固化过程经过三个阶段。在涂层形成的第一阶段,发生溶剂的剧烈蒸发。在第二阶段,在蒸发大约70%的溶剂之后,内部应力开始剧烈增长。在第三阶段,溶剂的浓度降低到接近平衡的值,并且其蒸发速率接近零。达到最大值的内部应力是稳定的。引入量为1-4%(按体积计)的增塑剂导致内应力的急剧降低。确定了内应力随聚合物涂层厚度的增加而线性增加。给出了涂层厚度与内应力关系的数学模型。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Stresses of Coatings Based on a Solution of Expanded Polystyrene DuringCuring
The purpose of the paper is to evaluate the crack resistance of a coating based on a solution of expanded polystyrene. Information is provided on the stress state of coatings based on a solution of expanded polystyrene depending on the time of curing, the thickness of the coating. It is established, that the process of curing polymer coatings passes through three stages. On the first stage of coating formation, intensive evaporation of the solvent occurs. In the second stage - after evaporative of approximately 70% of the solvent, an intensive growth of internal stresses begins. In the third stage, the concentration of the solvent is reduced to a value close to equilibrium and its evaporation rate approaches zero. Internal stresses, having reached a maximum value are stabilized. The introduction of a plasticizer in an amount of 1-4% (by volume) causes a sharp decrease in internal stresses. It is established, that internal stresses increase linearly with increasing polymer coating thickness. A mathematical model of the dependence of internal stresses on coating thickness is given.
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