静态顶空气相色谱法测定富含脂肪食品中己醛作为脂质氧化标志物的含量

IF 0.5 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Chemija Pub Date : 2020-04-21 DOI:10.6001/chemija.v31i2.4221

V. Vickackaite, Gintarė Pipiraitė, Vilius Poškus, Ingrida Jurkutė, B. Bugelytė

{"title":"静态顶空气相色谱法测定富含脂肪食品中己醛作为脂质氧化标志物的含量","authors":"V. Vickackaite, Gintarė Pipiraitė, Vilius Poškus, Ingrida Jurkutė, B. Bugelytė","doi":"10.6001/chemija.v31i2.4221","DOIUrl":null,"url":null,"abstract":"Department of Analytical and Environmental Chemistry, Vilnius University, 24 Naugarduko Street, 03225 Vilnius, Lithuania Static headspace gas chromatographic method for determination of hexanal as a marker of lipid oxidation was developed. Tetradecane was suggested as a matrix for hexanal release from the sample. Sample equilibration temperature and time, tetradecane volume, injection time were optimized. Benzaldehyde was selected as an internal standard. Under the optimized conditions quality parameters were determined. The calibration curve was linear in the concentration range from 25 μg l–1 to 2 g l–1, the detection limit was 15 μg l–1, RSD was determined by five replication analysis with hexanal concentration 0.1 g l–1 and was 1.2%. The technique was applied for hexanal determination in potato chips and fried potatoes.","PeriodicalId":9720,"journal":{"name":"Chemija","volume":" ","pages":""},"PeriodicalIF":0.5000,"publicationDate":"2020-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Static headspace gas chromatographic determination of hexanal as a marker of lipid oxidation in fat-rich food\",\"authors\":\"V. Vickackaite, Gintarė Pipiraitė, Vilius Poškus, Ingrida Jurkutė, B. Bugelytė\",\"doi\":\"10.6001/chemija.v31i2.4221\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Department of Analytical and Environmental Chemistry, Vilnius University, 24 Naugarduko Street, 03225 Vilnius, Lithuania Static headspace gas chromatographic method for determination of hexanal as a marker of lipid oxidation was developed. Tetradecane was suggested as a matrix for hexanal release from the sample. Sample equilibration temperature and time, tetradecane volume, injection time were optimized. Benzaldehyde was selected as an internal standard. Under the optimized conditions quality parameters were determined. The calibration curve was linear in the concentration range from 25 μg l–1 to 2 g l–1, the detection limit was 15 μg l–1, RSD was determined by five replication analysis with hexanal concentration 0.1 g l–1 and was 1.2%. The technique was applied for hexanal determination in potato chips and fried potatoes.\",\"PeriodicalId\":9720,\"journal\":{\"name\":\"Chemija\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2020-04-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemija\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.6001/chemija.v31i2.4221\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemija","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.6001/chemija.v31i2.4221","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 3

摘要

立陶宛维尔纽斯Naugarduko街24号维尔纽斯大学分析与环境化学系，邮编03225。建立了测定己醛作为脂质氧化标志物的静态顶空气相色谱法。十四烷被认为是从样品中释放己醛的基质。对样品平衡温度和时间、十四烷体积、注射时间进行了优化。选择苯甲醛作为内标。在优化的条件下确定了质量参数。在25μg l–1至2 g l–l–1的浓度范围内，校准曲线呈线性，检测限为15μg l-1，用己醛浓度为0.1 g l–-1的五次重复分析法测定RSD，RSD为1.2%。该技术用于薯片和炸土豆中己醛的测定。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Static headspace gas chromatographic determination of hexanal as a marker of lipid oxidation in fat-rich food

Department of Analytical and Environmental Chemistry, Vilnius University, 24 Naugarduko Street, 03225 Vilnius, Lithuania Static headspace gas chromatographic method for determination of hexanal as a marker of lipid oxidation was developed. Tetradecane was suggested as a matrix for hexanal release from the sample. Sample equilibration temperature and time, tetradecane volume, injection time were optimized. Benzaldehyde was selected as an internal standard. Under the optimized conditions quality parameters were determined. The calibration curve was linear in the concentration range from 25 μg l–1 to 2 g l–1, the detection limit was 15 μg l–1, RSD was determined by five replication analysis with hexanal concentration 0.1 g l–1 and was 1.2%. The technique was applied for hexanal determination in potato chips and fried potatoes.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Chemija 化学-化学综合

CiteScore

1.30

自引率

16.70%

发文量

审稿时长

>12 weeks

期刊介绍： Chemija publishes original research articles and reviews from all branches of modern chemistry, including physical, inorganic, analytical, organic, polymer chemistry, electrochemistry, and multidisciplinary approaches.