沸石催化松木热解的可再生能源

Eksergi Pub Date : 2022-04-05 DOI:10.31315/e.v19i1.4564
Zubaidi Achmad, Abdullah Kunta Arsa, B. Alfitamara, Alfia Virgiandini
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引用次数: 1

摘要

随着无法更新的化石能源储量的减少,可再生能源成为一个热点问题。为了应对这些能源可用性的挑战,在松木的高温裂解过程中进行了一项研究,以获得燃料油或所谓的热解。本研究的目的是确定热解结果的产率、物理性质和热值。热解过程是通过改变丝光沸石型沸石催化剂的百分比来完成的,所述丝光沸石型催化剂的百分比高达0%b/b、2%b/b和4%b/b,质量为100克松木,通过将每个样品筛分至50目。使用前,催化剂通过在500°C的温度下加热进行物理活化,并使用HCl进行化学活化,以提高沸石的活性。在400°C、450°C、500°C和550°C下进行热解。经过分析,在500°C的温度下,生物油获得了催化剂4%b/b质量的43.77142%的最佳产率。以密度1.094723 g/ml、2.96 cP粘度和58°C闪点的形式获得的物理性能。在催化剂用量为4%、反应温度为550°C的条件下,最高热值为26045.50 kJ/kg。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Renewable Energy from Pyrolysis of Pine Wood with Zeolite Catalyst
Renewable energy becomes a hot issue on the decrease of fossil energy reserves that can not be renewed. To answer the challenge of the availability of these energy a study was performed in a high-temperature cracking process from pine wood to obtain fuel oil or so-called pyrolysis. The purpose of this study was to determine the yield, physical properties, and the calorific value of the pyrolysis results. Pyrolysis process is done by varying the percentage of mordenite-type zeolite catalyst as much as  0% b/b, 2% b/b, and 4% b/b, with a mass of 100 grams of pine wood that passes sieving each sample to 50 mesh. Before use, the catalysts physically activated by heating at a temperature of 500°C and chemically activated using HCl to enhance the activity of the zeolite. Pyrolysis carried out at 400°C, 450°C, 500°C, and 550°C. After the analysis, bio-oil obtained optimum yield of 43.77142% by mass of the catalyst 4% b/b and a temperature of 500 °C. Physical properties obtained in the form of density 1.094723 g/ml, 2.96 cP viscosity, and 58°C flash point. While the highest calorific value on the condition of the catalyst 4% and the reaction temperature 550°C is 26045.50 kJ/kg.
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