{"title":"HCl/γ-Al2O3和HCl/Ni/γ-Al2O3催化剂对棕榈油裂解的影响","authors":"Alda Titania Dewanti, Rismawati Rasyid, R. Kalla","doi":"10.15408/jkv.v8i2.25774","DOIUrl":null,"url":null,"abstract":"Fuel oil has a deficit every year. Therefore, a substitute fuel is needed, which can be obtained more efficiently. One of the alternative fuels that have been widely researched is biofuel. Catalytic cracking is a method of producing biofuels such as biogasoline (C5-C9), bioavtur (C10-C15) and green diesel (C16-C22). This research aims to produce biofuels by catalytic cracking of palm oil using HCl/γ-Al2O3 and HCl/Ni/γ-Al2O3 catalysts (1, 3, 5 and 7%). The catalyst was prepared by wet impregnation and characterized by x-ray diffraction, Brunauer Emmett teller and ASTM-D664. The reaction cracking process was operated at a constant temperature of 370 °C, 50 ml volume, and 1 atm pressure. The best catalyst for cracking palm oil is HCl/Ni/γ-Al2O3 (5%) with a yield of 81%, selectivity to biogasoline at 6.41%, bioavtur at 33.81%, and green diesel at 20.33%.","PeriodicalId":17786,"journal":{"name":"Jurnal Kimia Valensi","volume":" ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Effect of HCl/γ-Al2O3 and HCl/Ni/γ-Al2O3 Catalyst on The Cracking of Palm Oil\",\"authors\":\"Alda Titania Dewanti, Rismawati Rasyid, R. Kalla\",\"doi\":\"10.15408/jkv.v8i2.25774\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Fuel oil has a deficit every year. Therefore, a substitute fuel is needed, which can be obtained more efficiently. One of the alternative fuels that have been widely researched is biofuel. Catalytic cracking is a method of producing biofuels such as biogasoline (C5-C9), bioavtur (C10-C15) and green diesel (C16-C22). This research aims to produce biofuels by catalytic cracking of palm oil using HCl/γ-Al2O3 and HCl/Ni/γ-Al2O3 catalysts (1, 3, 5 and 7%). The catalyst was prepared by wet impregnation and characterized by x-ray diffraction, Brunauer Emmett teller and ASTM-D664. The reaction cracking process was operated at a constant temperature of 370 °C, 50 ml volume, and 1 atm pressure. The best catalyst for cracking palm oil is HCl/Ni/γ-Al2O3 (5%) with a yield of 81%, selectivity to biogasoline at 6.41%, bioavtur at 33.81%, and green diesel at 20.33%.\",\"PeriodicalId\":17786,\"journal\":{\"name\":\"Jurnal Kimia Valensi\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-11-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Jurnal Kimia Valensi\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15408/jkv.v8i2.25774\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Jurnal Kimia Valensi","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15408/jkv.v8i2.25774","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Effect of HCl/γ-Al2O3 and HCl/Ni/γ-Al2O3 Catalyst on The Cracking of Palm Oil
Fuel oil has a deficit every year. Therefore, a substitute fuel is needed, which can be obtained more efficiently. One of the alternative fuels that have been widely researched is biofuel. Catalytic cracking is a method of producing biofuels such as biogasoline (C5-C9), bioavtur (C10-C15) and green diesel (C16-C22). This research aims to produce biofuels by catalytic cracking of palm oil using HCl/γ-Al2O3 and HCl/Ni/γ-Al2O3 catalysts (1, 3, 5 and 7%). The catalyst was prepared by wet impregnation and characterized by x-ray diffraction, Brunauer Emmett teller and ASTM-D664. The reaction cracking process was operated at a constant temperature of 370 °C, 50 ml volume, and 1 atm pressure. The best catalyst for cracking palm oil is HCl/Ni/γ-Al2O3 (5%) with a yield of 81%, selectivity to biogasoline at 6.41%, bioavtur at 33.81%, and green diesel at 20.33%.