{"title":"缓冲溶液中2-氨基十二烷基吡啶-5-硼酸钠盐和2-氨基十二烷基吡啶-5-硼酸钠盐的自组装研究","authors":"Sumita Roy, Monali Maiti, Siddhartha Das","doi":"10.18311/jsst/2021/25053","DOIUrl":null,"url":null,"abstract":"Boronic acid based amphiphiles are new generation green surfactant materials because they degrade to produce environmentally friendly boric acid. This study describes the interfacial property as well as aggregation behaviour of two pyridine based boronic acid amphiphiles containing amide linkage in hydrocarbon chain named sodium salt of 2-amidodecyl pyridine-5-boronic acid (SADPB) and sodium salt of 2-amidododecyl pyridine-5-boronic acid (SADDPB). Tensiometry study was executed for investigation of interfacial properties of pyiridine based boronic acid derivatives. Polarity and viscosity of the microenvironment of aggregates was investigated using fluorescence technique. DLS measurement suggested size of the assemblies of SADDPB is larger than SADPB in solutions. XRD technique was employed to examine arrangement of the hydrophobic tails in the bilayer aggregates. TEM technique was utilised to scrutinize aggregate morphology in solutions. The findings showed prospect of these amphiphiles to be applicable as drug carrier in pharmaceutical industries.","PeriodicalId":17031,"journal":{"name":"Journal of Surface Science and Technology","volume":" ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Self-Assembly Study of Sodium Salt of 2-Amidodecyl Pyridine-5-Boronic Acid and Sodium Salt of 2-Amidododecyl Pyridine-5-Boronic Acid in Buffer Solution\",\"authors\":\"Sumita Roy, Monali Maiti, Siddhartha Das\",\"doi\":\"10.18311/jsst/2021/25053\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Boronic acid based amphiphiles are new generation green surfactant materials because they degrade to produce environmentally friendly boric acid. This study describes the interfacial property as well as aggregation behaviour of two pyridine based boronic acid amphiphiles containing amide linkage in hydrocarbon chain named sodium salt of 2-amidodecyl pyridine-5-boronic acid (SADPB) and sodium salt of 2-amidododecyl pyridine-5-boronic acid (SADDPB). Tensiometry study was executed for investigation of interfacial properties of pyiridine based boronic acid derivatives. Polarity and viscosity of the microenvironment of aggregates was investigated using fluorescence technique. DLS measurement suggested size of the assemblies of SADDPB is larger than SADPB in solutions. XRD technique was employed to examine arrangement of the hydrophobic tails in the bilayer aggregates. TEM technique was utilised to scrutinize aggregate morphology in solutions. The findings showed prospect of these amphiphiles to be applicable as drug carrier in pharmaceutical industries.\",\"PeriodicalId\":17031,\"journal\":{\"name\":\"Journal of Surface Science and Technology\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-02-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Surface Science and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.18311/jsst/2021/25053\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"Materials Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Surface Science and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.18311/jsst/2021/25053","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Materials Science","Score":null,"Total":0}
Self-Assembly Study of Sodium Salt of 2-Amidodecyl Pyridine-5-Boronic Acid and Sodium Salt of 2-Amidododecyl Pyridine-5-Boronic Acid in Buffer Solution
Boronic acid based amphiphiles are new generation green surfactant materials because they degrade to produce environmentally friendly boric acid. This study describes the interfacial property as well as aggregation behaviour of two pyridine based boronic acid amphiphiles containing amide linkage in hydrocarbon chain named sodium salt of 2-amidodecyl pyridine-5-boronic acid (SADPB) and sodium salt of 2-amidododecyl pyridine-5-boronic acid (SADDPB). Tensiometry study was executed for investigation of interfacial properties of pyiridine based boronic acid derivatives. Polarity and viscosity of the microenvironment of aggregates was investigated using fluorescence technique. DLS measurement suggested size of the assemblies of SADDPB is larger than SADPB in solutions. XRD technique was employed to examine arrangement of the hydrophobic tails in the bilayer aggregates. TEM technique was utilised to scrutinize aggregate morphology in solutions. The findings showed prospect of these amphiphiles to be applicable as drug carrier in pharmaceutical industries.
期刊介绍:
The Indian Society for Surface Science and Technology is an organization for the cultivation, interaction and dissemination of knowledge in the field of surface science and technology. It also strives to promote Industry-Academia interaction