等离子体化学氮化钛负载Pt实现室温CO高效氧化

E. N. Kabachkov, E. N. Kurkin, N. N. Vershinin, I. L. Balikhin, V. Berestenko, A. Michtchenko, Y. Shulga
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引用次数: 2

摘要

采用在氮化钛(TiN)上沉积铂的方法合成了一氧化碳氧化催化剂。在氮气微波等离子体流中对四氯化钛进行氢还原,得到了两种平均粒径分别为18和36 nm的衬底。用x射线光电子能谱(XPS)对催化剂表面进行了研究。在9-15 wt.% Pt负载TiN催化剂上,CO的氧化速率比在比表面积为30 m2/g的铂黑上的氧化速率高120倍。这种催化剂在催化空气净化系统中应用前景广阔。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Pt Supported on Plasma-Chemical Titanium Nitride for Efficient Room-Temperature CO Oxidation
Catalysts of carbon monoxide oxidation were synthesized by deposition of platinum on titanium nitride (TiN). Two substrates with an average particle size of 18 and 36 nm were obtained by hydrogen reduction of titanium tetrachloride in a stream of microwave plasma of nitrogen. The surface of the catalysts was studied by X-ray photoelectron spectroscopy (XPS). The CO oxidation rate on the 9-15 wt.% Pt loaded TiN catalysts was found to be 120 times higher than that on platinum black with a specific surface of 30 m2/g. Such catalysts are promising for use in catalytic air purification systems.
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