{"title":"K2O:Al2O3配比对硅酸锂微晶玻璃结晶现象及微观结构的影响","authors":"Santa Kolay, P. Bhargava","doi":"10.1080/0371750X.2021.2001693","DOIUrl":null,"url":null,"abstract":"K2O plays an important role as glass modifier in glass systems. In the present study,the effect of K2O:Al2O3 ratio on crystallization and microstructural evolution in Li2O-SiO2- K2O-MgO-Al2O3-ZnO-ZrO2-P2O5 glass system has been reported. K2O mol% has been varied from 1 to 3 mol% while keeping Al2O3 at 2 mol%. The glass structure was analyzed by MAS-NMR spectroscopy. Heat treated glass systems were studied by using XRD, SEM and DTA to analyse the sintering and crystallization behavior. Increased amount of K2O modified the role of Al2O3, which acted as glass network former and formed [AlO4/2] tetrahedron unit, which eventually polymerized the glass structure. Consequently, lithium disilicate (LS2) crystallization was suppressed and crystallization of lithium metasilicate (LS) was promoted. As a result, while in the sample with 1 mol% K2O LS2 appeared as the main crystalline phase and LS as minor phase, 3 mol% K2O samples did not show any lithium disilicate throughout the sintering temperature range. The K2O:Al2O3 ratio did not have a significant impact on densification of these glass-ceramics. GRAPHICAL ABSTRACT","PeriodicalId":23233,"journal":{"name":"Transactions of the Indian Ceramic Society","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2021-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Effect of K2O:Al2O3 Ratio on Crystallization Phenomena and Microstructure of Lithium Silicate Glass-Ceramics\",\"authors\":\"Santa Kolay, P. Bhargava\",\"doi\":\"10.1080/0371750X.2021.2001693\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"K2O plays an important role as glass modifier in glass systems. In the present study,the effect of K2O:Al2O3 ratio on crystallization and microstructural evolution in Li2O-SiO2- K2O-MgO-Al2O3-ZnO-ZrO2-P2O5 glass system has been reported. K2O mol% has been varied from 1 to 3 mol% while keeping Al2O3 at 2 mol%. The glass structure was analyzed by MAS-NMR spectroscopy. Heat treated glass systems were studied by using XRD, SEM and DTA to analyse the sintering and crystallization behavior. Increased amount of K2O modified the role of Al2O3, which acted as glass network former and formed [AlO4/2] tetrahedron unit, which eventually polymerized the glass structure. Consequently, lithium disilicate (LS2) crystallization was suppressed and crystallization of lithium metasilicate (LS) was promoted. As a result, while in the sample with 1 mol% K2O LS2 appeared as the main crystalline phase and LS as minor phase, 3 mol% K2O samples did not show any lithium disilicate throughout the sintering temperature range. The K2O:Al2O3 ratio did not have a significant impact on densification of these glass-ceramics. GRAPHICAL ABSTRACT\",\"PeriodicalId\":23233,\"journal\":{\"name\":\"Transactions of the Indian Ceramic Society\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2021-10-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of the Indian Ceramic Society\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1080/0371750X.2021.2001693\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of the Indian Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/0371750X.2021.2001693","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Effect of K2O:Al2O3 Ratio on Crystallization Phenomena and Microstructure of Lithium Silicate Glass-Ceramics
K2O plays an important role as glass modifier in glass systems. In the present study,the effect of K2O:Al2O3 ratio on crystallization and microstructural evolution in Li2O-SiO2- K2O-MgO-Al2O3-ZnO-ZrO2-P2O5 glass system has been reported. K2O mol% has been varied from 1 to 3 mol% while keeping Al2O3 at 2 mol%. The glass structure was analyzed by MAS-NMR spectroscopy. Heat treated glass systems were studied by using XRD, SEM and DTA to analyse the sintering and crystallization behavior. Increased amount of K2O modified the role of Al2O3, which acted as glass network former and formed [AlO4/2] tetrahedron unit, which eventually polymerized the glass structure. Consequently, lithium disilicate (LS2) crystallization was suppressed and crystallization of lithium metasilicate (LS) was promoted. As a result, while in the sample with 1 mol% K2O LS2 appeared as the main crystalline phase and LS as minor phase, 3 mol% K2O samples did not show any lithium disilicate throughout the sintering temperature range. The K2O:Al2O3 ratio did not have a significant impact on densification of these glass-ceramics. GRAPHICAL ABSTRACT
期刊介绍:
Transactions of the Indian Ceramic Society is a quarterly Journal devoted to current scientific research, technology and industry-related news on glass and ceramics. The Journal covers subjects such as the chemical, mechanical, optical, electronic and spectroscopic properties of glass and ceramics, and characterization of materials belonging to this family.
The Editor invites original research papers, topical reviews, opinions and achievements, as well as industry profiles for publication. The contributions should be accompanied by abstracts, keywords and other details, as outlined in the Instructions for Authors section. News, views and other comments on activities of specific industries and organizations, and also analyses of industrial scenarios are also welcome.