堆肥样品pH值和电导率测量的方法学研究

IF 0.2 Q4 CHEMISTRY, MULTIDISCIPLINARY
F. Marrero, José Prato, Y. L. Cruz, Adriana Sánchez
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引用次数: 5

摘要

本文描述了堆肥/溶剂关系对pH和电导率(CE)测量的影响,使用水和cacl2 0.01 M作为萃取剂,在萃取液悬浮液和离心上清液中。根据结果,pH CaCl2似乎更独立于萃取剂的数量,与水萃取物的测量相反,它随着稀释而增加,用二次模型描述。因此,测量必须在曲线斜率最小或为零的地方进行,并且在测量与萃取剂数量无关的地方进行。对于含水萃取物,在堆肥/萃取物的比例大于1:8时发生,对于氯化钙萃取物,在比例大于1:5时发生。pH H2O高于pH CaCl2,说明CaCl2是较好的酸性萃取剂。EC测量也显示出多项式行为,因此必须在堆肥/萃取剂大于1:6的关系上进行,其中EC值与萃取剂的数量更加独立。EC可在cacl2萃取液、悬浮液或上清液中进行,并分别进行空白校正。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Estudio metodológico sobre la medición de pH y conductividad eléctrica en muestras de compost
The present paper describes the influence of compost/solvent relations on pH and electric conductivity (CE) measurements, using water and CaCl 2 0.01 M as extractants, in the extract suspension as well as in centrifuged supernatant. According to the results, pH CaCl2 seems to be more independent of extractant quantity, contrarily to aqueous extract measurements, which increases with dilution, described by a quadratic model. As a consequence, measurement must be performed where the curve slope is minimum or null, and where the measurement becomes independent of extractant quantity. For aqueous extract, it happens at relations compost/extractant greater than 1:8, and for CaCl 2 extracts, greater than 1:5. pH H2O is higher than pH CaCl2 showing that CaCl 2 is a better acidity extractant. EC measurements also show polynomical behavior, therefore must be performed on relations compost/extractant greater than 1:6, where EC values are more independent of extractant quantity. EC could be performed in CaCl 2 extract, suspension or supernatant, with respective blank correction.
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来源期刊
Revista Colombiana de Quimica
Revista Colombiana de Quimica CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.50
自引率
0.00%
发文量
12
期刊介绍: The Revista Colombiana de Química - Colombian Journal of Chemistry (Rev. Colomb. Quim.) Is a peer-reviewed scientific journal of the Department of Chemistry, Faculty of Sciences of the Universidad Nacional de Colombia, Bogotá. It currently publishes three volumes per year: January-April, May-August and September-December. All the content published by the Journal (available online) is under a Creative Commons attribution license type BY 4.0, that allows any person or entity in the world to freely access the content, share it, download it, adapt it or make derivative works without any restriction, provided that it adequately indicates the credit to the authors and to the Colombian Journal of Chemistry.
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