染料分子与硫化镉纳米棒在染料敏化太阳能电池(DSSCs)中的作用

Entidhar A. Alkuam
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引用次数: 5

摘要

在氟氧化锡(FTO)衬底上,采用水热法在200℃下合成了排列六方硫化镉纳米棒(CdSNR)。采用不同类型的染料分子,制备并设计了基于聚苯胺(PANI)和聚(3,4-乙烯二氧基噻吩)/聚苯乙烯磺酸盐(PEDOT:PSS)纳米复合导电聚合物的光电极核壳CdSNR阵列染料敏化太阳能电池(DSSCs)。利用扫描电镜(SEM)、拉曼散射(Raman scattering)、能谱(EDS)、紫外-可见吸收光谱(UV-Vis absorption spectroscopy)、x射线衍射(XRD)和光电流-电压(J-V)特性对DSSCs进行了表征。结果表明,在照度(AM 1.5 G)下,与其他天然染料敏化的CdSNR/PANI-PEDOT:PSS器件相比,以0.91%的钌(染料N-719)敏化CdSNR/PANI-PEDOT:PSS器件获得了较高的功率转换能(PCE)和4.21 mA/cm2的短路电流密度(Jsc)。CdSNR/PANI-PEDOT:PSS-N719器件的高性能归功于N719的广泛吸收和光稳定性。研究结果表明,N719的CdSNR具有较低的制造成本和良好的吸收性能,是光伏器件的理想候选材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
An Effective of Dye Molecules with Cadmium Sulfide Nanorods in Dye Sensitized Solar Cell (DSSCs)
The aligned hexagonal cadmium sulfide nanorods (CdSNR) have been synthe-sized by hydrothermal technique at 200ºC on fluorine tin oxide (FTO) sub-strates. Dye sensitized solar cells (DSSCs) based on the photoelectrode core-shell CdSNR array with conductive polymers nanocomposite of polyaniline (PANI) and poly(3,4-ethylenedioxyl-thiophene)/poly(styrene-sulfonate) (PEDOT:PSS) were fabricated and designed with different types of dye molecules. DSSCs were characterized utilizing scanning electron microscopy (SEM), Raman scattering, energy dispersive spectroscopy (EDS), UV-Vis absorption spectroscopy, X-ray diffraction (XRD), and photocurrent-voltage (J-V) characteristic. Results show that under illumination (AM 1.5 G), the high power conversion energy (PCE) was achieved for CdSNR/PANI-PEDOT:PSS device when it sensitized with ruthenium (II) (dye N-719) of 0.91% and a short circuit current density (Jsc) of 4.21 mA/cm2 in comparison with the other devices, which sensitized with natural dyes. The high performance of the CdSNR/PANI-PEDOT:PSS-N719 device attributed to the wide range of absorption and photostability for N719. This work shows that the CdSNR with N719 can be appropriate candidate for photovoltaics device for their low cost fabrication procedure and excellent absorption.
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