Vasudevarao Pasala, S. Maddukuri, V. Sethuraman, Rekha Lankipalli, Devi Gajula, Venkateswarlu Manne
{"title":"NMP在(LiNi0.80Co0.15Al0.05)(NCA)阴极浆料中的分步添加及其对锂离子电池的流变、机械强度和电化学性能的研究","authors":"Vasudevarao Pasala, S. Maddukuri, V. Sethuraman, Rekha Lankipalli, Devi Gajula, Venkateswarlu Manne","doi":"10.33961/jecst.2023.00115","DOIUrl":null,"url":null,"abstract":"For electrode stability and the electrochemical performance of the Li-ion cell, it is essential that the active ingredients and unique additives in the polymer binder be well dispersed with the solvent-based slurry. The efficient procedure used to cre-ate the slurry affects the rheological characteristics of the electrode slurry. When successively adding different steps of N-methyl-2-pyrrolidone (NMP) solvent to the cathode composition, it is evenly disseminated. The electrochemical performance of the Li-ion cells and the electrodes made with slurry formed by single step and multiple steps of addition of NMP solvent are examined. To preform rheological properties of cathode electrode slurry on Ni-rich Lithium Nickel-Cobalt-Alu-minum Oxide (LiNi 0.80 Co 0.15 Al 0.05 ) (NCA). Also, we investigate different step addition of electrode formation and mechanical strength characterization like peel strength. According to the EIS study, a multi-step electrode slurry has lower internal resistance than a single-step electrode slurry, which results in better electrical characteristics and efficiency. Further, micro-structure of electrodes is obtained electrochemical performance in the 18650 cylindrical cells with targeted capacity of 1.5 Ah. The slurry of electrodes prepared by single step and multiple steps of addition of NMP solvent and its effect on the fabrication of 1.5 Ah cells. A three-step solvent addition on slurry has been found to be a lower internal resistance than a single-step electrode slurry as confirmed by the EIS analysis","PeriodicalId":15542,"journal":{"name":"Journal of electrochemical science and technology","volume":" ","pages":""},"PeriodicalIF":2.2000,"publicationDate":"2023-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Studies on Multi-step Addition of NMP in (LiNi0.80Co0.15Al0.05) (NCA) Cathode Slurry Preparation and its Rheological, Mechanical Strength and Electrochemical Properties for Li-ion Cells\",\"authors\":\"Vasudevarao Pasala, S. Maddukuri, V. Sethuraman, Rekha Lankipalli, Devi Gajula, Venkateswarlu Manne\",\"doi\":\"10.33961/jecst.2023.00115\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"For electrode stability and the electrochemical performance of the Li-ion cell, it is essential that the active ingredients and unique additives in the polymer binder be well dispersed with the solvent-based slurry. The efficient procedure used to cre-ate the slurry affects the rheological characteristics of the electrode slurry. When successively adding different steps of N-methyl-2-pyrrolidone (NMP) solvent to the cathode composition, it is evenly disseminated. The electrochemical performance of the Li-ion cells and the electrodes made with slurry formed by single step and multiple steps of addition of NMP solvent are examined. To preform rheological properties of cathode electrode slurry on Ni-rich Lithium Nickel-Cobalt-Alu-minum Oxide (LiNi 0.80 Co 0.15 Al 0.05 ) (NCA). Also, we investigate different step addition of electrode formation and mechanical strength characterization like peel strength. According to the EIS study, a multi-step electrode slurry has lower internal resistance than a single-step electrode slurry, which results in better electrical characteristics and efficiency. Further, micro-structure of electrodes is obtained electrochemical performance in the 18650 cylindrical cells with targeted capacity of 1.5 Ah. The slurry of electrodes prepared by single step and multiple steps of addition of NMP solvent and its effect on the fabrication of 1.5 Ah cells. A three-step solvent addition on slurry has been found to be a lower internal resistance than a single-step electrode slurry as confirmed by the EIS analysis\",\"PeriodicalId\":15542,\"journal\":{\"name\":\"Journal of electrochemical science and technology\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2023-06-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of electrochemical science and technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.33961/jecst.2023.00115\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of electrochemical science and technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.33961/jecst.2023.00115","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Studies on Multi-step Addition of NMP in (LiNi0.80Co0.15Al0.05) (NCA) Cathode Slurry Preparation and its Rheological, Mechanical Strength and Electrochemical Properties for Li-ion Cells
For electrode stability and the electrochemical performance of the Li-ion cell, it is essential that the active ingredients and unique additives in the polymer binder be well dispersed with the solvent-based slurry. The efficient procedure used to cre-ate the slurry affects the rheological characteristics of the electrode slurry. When successively adding different steps of N-methyl-2-pyrrolidone (NMP) solvent to the cathode composition, it is evenly disseminated. The electrochemical performance of the Li-ion cells and the electrodes made with slurry formed by single step and multiple steps of addition of NMP solvent are examined. To preform rheological properties of cathode electrode slurry on Ni-rich Lithium Nickel-Cobalt-Alu-minum Oxide (LiNi 0.80 Co 0.15 Al 0.05 ) (NCA). Also, we investigate different step addition of electrode formation and mechanical strength characterization like peel strength. According to the EIS study, a multi-step electrode slurry has lower internal resistance than a single-step electrode slurry, which results in better electrical characteristics and efficiency. Further, micro-structure of electrodes is obtained electrochemical performance in the 18650 cylindrical cells with targeted capacity of 1.5 Ah. The slurry of electrodes prepared by single step and multiple steps of addition of NMP solvent and its effect on the fabrication of 1.5 Ah cells. A three-step solvent addition on slurry has been found to be a lower internal resistance than a single-step electrode slurry as confirmed by the EIS analysis