NMP在(LiNi0.80Co0.15Al0.05)(NCA)阴极浆料中的分步添加及其对锂离子电池的流变、机械强度和电化学性能的研究

IF 2.2 4区 工程技术 Q3 ELECTROCHEMISTRY
Vasudevarao Pasala, S. Maddukuri, V. Sethuraman, Rekha Lankipalli, Devi Gajula, Venkateswarlu Manne
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引用次数: 1

摘要

为了电极稳定性和锂离子电池的电化学性能,聚合物粘合剂中的活性成分和独特添加剂必须与溶剂基浆料充分分散。用于生成浆料的有效程序影响电极浆料的流变特性。当将不同步骤的N-甲基-2-吡咯烷酮(NMP)溶剂连续添加到阴极组合物中时,其被均匀地分散。考察了由NMP溶剂的一步和多步添加形成的浆料制成的锂离子电池和电极的电化学性能。在富镍锂镍钴铝氧化物(LiNi0.80Co0.15Al0.05)(NCA)上制备阴极浆料的流变性能。此外,我们还研究了电极形成的不同步骤添加和机械强度表征,如剥离强度。根据EIS研究,多级电极浆料比单步电极浆料具有更低的内阻,从而产生更好的电气特性和效率。此外,在目标容量为1.5Ah的18650个圆柱形电池中获得了电极的微观结构的电化学性能。通过单步和多步添加NMP溶剂制备的电极浆料及其对1.5Ah电池制造的影响。EIS分析证实,在浆料上添加三步溶剂比单步电极浆料具有更低的内阻
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Studies on Multi-step Addition of NMP in (LiNi0.80Co0.15Al0.05) (NCA) Cathode Slurry Preparation and its Rheological, Mechanical Strength and Electrochemical Properties for Li-ion Cells
For electrode stability and the electrochemical performance of the Li-ion cell, it is essential that the active ingredients and unique additives in the polymer binder be well dispersed with the solvent-based slurry. The efficient procedure used to cre-ate the slurry affects the rheological characteristics of the electrode slurry. When successively adding different steps of N-methyl-2-pyrrolidone (NMP) solvent to the cathode composition, it is evenly disseminated. The electrochemical performance of the Li-ion cells and the electrodes made with slurry formed by single step and multiple steps of addition of NMP solvent are examined. To preform rheological properties of cathode electrode slurry on Ni-rich Lithium Nickel-Cobalt-Alu-minum Oxide (LiNi 0.80 Co 0.15 Al 0.05 ) (NCA). Also, we investigate different step addition of electrode formation and mechanical strength characterization like peel strength. According to the EIS study, a multi-step electrode slurry has lower internal resistance than a single-step electrode slurry, which results in better electrical characteristics and efficiency. Further, micro-structure of electrodes is obtained electrochemical performance in the 18650 cylindrical cells with targeted capacity of 1.5 Ah. The slurry of electrodes prepared by single step and multiple steps of addition of NMP solvent and its effect on the fabrication of 1.5 Ah cells. A three-step solvent addition on slurry has been found to be a lower internal resistance than a single-step electrode slurry as confirmed by the EIS analysis
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来源期刊
CiteScore
6.30
自引率
8.10%
发文量
44
期刊介绍: Covering fields: - Batteries and Energy Storage - Biological Electrochemistry - Corrosion Science and Technology - Electroanalytical Chemistry and Sensor Technology - Electrocatalysis - Electrochemical Capacitors & Supercapcitors - Electrochemical Engineering - Electrodeposition and Surface Treatment - Environmental Science and Technology - Fuel Cells - Material Electrochemistry - Molecular Electrochemistry and Organic Electrochemistry - Physical Electrochemistry - Solar Energy Conversion and Photoelectrochemistry
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