碘桥接双核铜(I)与3,6-二(二甲氨基)吖啶配合物的晶体结构

IF 0.1 Q4 CRYSTALLOGRAPHY
Misaki Ohkita, Ayako Fujiwara, T. Nishiyama, M. Maekawa, T. Kuroda–Sowa, T. Okubo
{"title":"碘桥接双核铜(I)与3,6-二(二甲氨基)吖啶配合物的晶体结构","authors":"Misaki Ohkita, Ayako Fujiwara, T. Nishiyama, M. Maekawa, T. Kuroda–Sowa, T. Okubo","doi":"10.2116/XRAYSTRUCT.37.29","DOIUrl":null,"url":null,"abstract":"Polynuclear metal complexes have attracted increasing attention in the field of materials science because of their characteristic chemical and/or physical properties based on the assembled structures of metal ions and organic ligands.1,2 In particular, polynuclear copper(I)-halide complexes have the advantage of creating unique functionalities based on the versatile crystal structures derived from the structural diversity in the coordination geometry of the d10 copper(I) ion. For example, it is known that many polynuclear copper(I) complexes show photoluminescent properties from various excited states, such as a triplet metal-toligand charge transfer excited state (3MLCT), triplet clustercentered excited state (3CC), and thermally activated delayedfluorescence (TADF).3–5 We also demonstrated that polynuclear copper(I) halide complexes exhibit semiconducting behavior based on the formation of energy bands. Therefore, it is important to create polynuclear copper(I)-halide complexes to develop the field of materials chemistry.6 Here, we employed an acridine derivative, bis(dimethylamino)acridine (dma-acd), to construct polynuclear copper(I) halide complexes. We found that the reaction of copper(I) iodide with dma-acd ligands produced a dinuclear copper(I)-iodide complex, as shown in Fig. 1. In this paper, we report on the crystal structure of this complex. A dinuclear copper(I) complex [Cu2I2(dma-acd)2] (1) was 2021 © The Japan Society for Analytical Chemistry","PeriodicalId":23922,"journal":{"name":"X-ray Structure Analysis Online","volume":null,"pages":null},"PeriodicalIF":0.1000,"publicationDate":"2021-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Crystal Structure of an Iodido-bridged Dinuclear Copper(I) Complex with 3,6-Bis(dimethylamino)acridine\",\"authors\":\"Misaki Ohkita, Ayako Fujiwara, T. Nishiyama, M. Maekawa, T. Kuroda–Sowa, T. Okubo\",\"doi\":\"10.2116/XRAYSTRUCT.37.29\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Polynuclear metal complexes have attracted increasing attention in the field of materials science because of their characteristic chemical and/or physical properties based on the assembled structures of metal ions and organic ligands.1,2 In particular, polynuclear copper(I)-halide complexes have the advantage of creating unique functionalities based on the versatile crystal structures derived from the structural diversity in the coordination geometry of the d10 copper(I) ion. For example, it is known that many polynuclear copper(I) complexes show photoluminescent properties from various excited states, such as a triplet metal-toligand charge transfer excited state (3MLCT), triplet clustercentered excited state (3CC), and thermally activated delayedfluorescence (TADF).3–5 We also demonstrated that polynuclear copper(I) halide complexes exhibit semiconducting behavior based on the formation of energy bands. Therefore, it is important to create polynuclear copper(I)-halide complexes to develop the field of materials chemistry.6 Here, we employed an acridine derivative, bis(dimethylamino)acridine (dma-acd), to construct polynuclear copper(I) halide complexes. We found that the reaction of copper(I) iodide with dma-acd ligands produced a dinuclear copper(I)-iodide complex, as shown in Fig. 1. In this paper, we report on the crystal structure of this complex. A dinuclear copper(I) complex [Cu2I2(dma-acd)2] (1) was 2021 © The Japan Society for Analytical Chemistry\",\"PeriodicalId\":23922,\"journal\":{\"name\":\"X-ray Structure Analysis Online\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.1000,\"publicationDate\":\"2021-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"X-ray Structure Analysis Online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2116/XRAYSTRUCT.37.29\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/XRAYSTRUCT.37.29","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0

摘要

多核金属配合物以金属离子和有机配体的组合结构为基础,具有独特的化学和物理性质,近年来在材料科学领域受到越来越多的关注。特别是,多核铜(I)-卤化物配合物具有基于d10铜(I)离子配位几何结构多样性衍生的多用途晶体结构创造独特功能的优势。例如,众所周知,许多多核铜(I)配合物在各种激发态下表现出光致发光特性,如三态金属-配体电荷转移激发态(3MLCT)、三态簇心激发态(3CC)和热激活延迟荧光(TADF)。我们还证明了多核铜(I)卤化物配合物基于能带的形成表现出半导体行为。因此,制备多核铜卤化物配合物对材料化学领域的发展具有重要意义在这里,我们采用吖啶衍生物,双(二甲氨基)吖啶(dma- add),构建多核铜(I)卤化物配合物。我们发现碘化铜(I)与dma- add配体反应生成双核碘化铜(I)配合物,如图1所示。本文报道了该配合物的晶体结构。一个双核铜(I)配合物[Cu2I2(dma- add)2](1)是2021©日本分析化学学会
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Crystal Structure of an Iodido-bridged Dinuclear Copper(I) Complex with 3,6-Bis(dimethylamino)acridine
Polynuclear metal complexes have attracted increasing attention in the field of materials science because of their characteristic chemical and/or physical properties based on the assembled structures of metal ions and organic ligands.1,2 In particular, polynuclear copper(I)-halide complexes have the advantage of creating unique functionalities based on the versatile crystal structures derived from the structural diversity in the coordination geometry of the d10 copper(I) ion. For example, it is known that many polynuclear copper(I) complexes show photoluminescent properties from various excited states, such as a triplet metal-toligand charge transfer excited state (3MLCT), triplet clustercentered excited state (3CC), and thermally activated delayedfluorescence (TADF).3–5 We also demonstrated that polynuclear copper(I) halide complexes exhibit semiconducting behavior based on the formation of energy bands. Therefore, it is important to create polynuclear copper(I)-halide complexes to develop the field of materials chemistry.6 Here, we employed an acridine derivative, bis(dimethylamino)acridine (dma-acd), to construct polynuclear copper(I) halide complexes. We found that the reaction of copper(I) iodide with dma-acd ligands produced a dinuclear copper(I)-iodide complex, as shown in Fig. 1. In this paper, we report on the crystal structure of this complex. A dinuclear copper(I) complex [Cu2I2(dma-acd)2] (1) was 2021 © The Japan Society for Analytical Chemistry
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
0.60
自引率
50.00%
发文量
17
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信