高抗硫酸镁复合水泥

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2018-04-18 DOI:10.3989/MC.2018.11316

A. Allahverdi, M. Akhondi, M. Mahinroosta

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引用次数: 5

摘要

研究了化学活性磷渣基复合水泥(CAPSCC)的抗硫酸镁性能。用磷渣(80 wt.%)、II型硅酸盐水泥(14 wt.%)和复合化学活化剂(6 wt.%)配制足够的砂浆试样，固化后暴露于5%硫酸镁溶液中。制备II型和V型硅酸盐水泥(PC2和PC5)砂浆试件进行对比。试验结果表明，暴露12个月后，PC2、PC5和CAPSCC的抗压强度分别降低43.5%、35.2和25.2%，长度膨胀率分别为0.136、0.110和0.026%，重量变化率分别为0.91、2.2和1.78%。x射线衍射和扫描电镜的补充研究表明，CAPSCC形成硫酸盐侵蚀产物的潜力非常低，尤其是钙矾石。结果证实，与PC2和PC5相比，CAPSCC具有较高的耐硫酸镁性能。

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A composite cement of high magnesium sulphate resistance

This study investigates the magnesium sulphate resistance of chemically activated phosphorus slag-based composite cement (CAPSCC). Enough mortar specimens were prepared from phosphorus slag (80 wt.%), type II Portland cement (14 wt.%), and compound chemical activator (6 wt.%) and were exposed to 5% magnesium sulphate solution after being cured. Mortar specimens of both type II and V Portland cements (PC2 and PC5) were also prepared and used for comparison purpose. According to the test results, after 12 months of exposure, PC2, PC5 and CAPSCC exhibited 43.5, 35.2 and 25.2% reduction in compressive strength, 0.136, 0.110, and 0.026% expansion in length, and 0.91, 2.2, and 1.78% change in weight, respectively. Complementary studies by X-ray diffractometry and scanning electron microscopy revealed that CAPSCC has a very low potential for the formation of sulphate attack products, especially ettringite. The results confirm a high magnesium sulphate resistance for CAPSCC compared to PC2 and PC5.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.