{"title":"碳粉煤灰的结构、形态和物理特性","authors":"Ricardo Parra, C. Carvajal, J. G. Cuaspud","doi":"10.17807/orbital.v15i2.18260","DOIUrl":null,"url":null,"abstract":"Carbon fly ash (CFA) is the principal industrial waste byproduct from the burning fossil fuel (coal combustion) for the thermal generation of electricity. CFA is a gray or black powdery solid that is constituted mostly metal oxides (Al, Si Fe and Ca), unburned carbon (UC) and other inorganic substance. The management of fly ash has thus been a matter of concern given the requirement of the large area of land for its disposal and potential of causing pollution of air, water, land and effects on human health. Physical and chemical characteristics of fly ash is important, as these characteristics influence its subsequent use and disposal. X-ray diffraction, and fluorescence, scanning microscopy with an energy dispersive spectroscopy, FTIR, BET was the common techniques employed to characterize FA. Characterization by XRD analysis identified the presence of quartz, mullite and sillimanite phases; while the FTIR results allowed the identification of vibrational bands, characteristic of Si-O-Si and Si-O bonds. The EDS analysis coupled to SEM allowed verifying that the composition of the samples is consistent with the results sought and that the morphological characteristics validate the proposed methodology. Surface area analyses (BET) showed that the fly ash possess an active area of 6.02 m2 · g-1. \n ","PeriodicalId":19680,"journal":{"name":"Orbital: The Electronic Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2023-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Structural, Morphological and Physical Characterization of Carbon Fly Ash\",\"authors\":\"Ricardo Parra, C. Carvajal, J. G. Cuaspud\",\"doi\":\"10.17807/orbital.v15i2.18260\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Carbon fly ash (CFA) is the principal industrial waste byproduct from the burning fossil fuel (coal combustion) for the thermal generation of electricity. CFA is a gray or black powdery solid that is constituted mostly metal oxides (Al, Si Fe and Ca), unburned carbon (UC) and other inorganic substance. The management of fly ash has thus been a matter of concern given the requirement of the large area of land for its disposal and potential of causing pollution of air, water, land and effects on human health. Physical and chemical characteristics of fly ash is important, as these characteristics influence its subsequent use and disposal. X-ray diffraction, and fluorescence, scanning microscopy with an energy dispersive spectroscopy, FTIR, BET was the common techniques employed to characterize FA. Characterization by XRD analysis identified the presence of quartz, mullite and sillimanite phases; while the FTIR results allowed the identification of vibrational bands, characteristic of Si-O-Si and Si-O bonds. The EDS analysis coupled to SEM allowed verifying that the composition of the samples is consistent with the results sought and that the morphological characteristics validate the proposed methodology. Surface area analyses (BET) showed that the fly ash possess an active area of 6.02 m2 · g-1. \\n \",\"PeriodicalId\":19680,\"journal\":{\"name\":\"Orbital: The Electronic Journal of Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2023-07-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Orbital: The Electronic Journal of Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.17807/orbital.v15i2.18260\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Orbital: The Electronic Journal of Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.17807/orbital.v15i2.18260","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Structural, Morphological and Physical Characterization of Carbon Fly Ash
Carbon fly ash (CFA) is the principal industrial waste byproduct from the burning fossil fuel (coal combustion) for the thermal generation of electricity. CFA is a gray or black powdery solid that is constituted mostly metal oxides (Al, Si Fe and Ca), unburned carbon (UC) and other inorganic substance. The management of fly ash has thus been a matter of concern given the requirement of the large area of land for its disposal and potential of causing pollution of air, water, land and effects on human health. Physical and chemical characteristics of fly ash is important, as these characteristics influence its subsequent use and disposal. X-ray diffraction, and fluorescence, scanning microscopy with an energy dispersive spectroscopy, FTIR, BET was the common techniques employed to characterize FA. Characterization by XRD analysis identified the presence of quartz, mullite and sillimanite phases; while the FTIR results allowed the identification of vibrational bands, characteristic of Si-O-Si and Si-O bonds. The EDS analysis coupled to SEM allowed verifying that the composition of the samples is consistent with the results sought and that the morphological characteristics validate the proposed methodology. Surface area analyses (BET) showed that the fly ash possess an active area of 6.02 m2 · g-1.
期刊介绍:
Orbital: The Electronic Journal of Chemistry is a quarterly scientific journal published by the Institute of Chemistry of the Universidade Federal de Mato Grosso do Sul, Brazil. Original contributions (in English) are welcome, which focus on all areas of Chemistry and their interfaces with Pharmacy, Biology, and Physics. Neither authors nor readers have to pay fees. The journal has an editorial team of scientists drawn from regions throughout Brazil and world, ensuring high standards for the texts published. The following categories are available for contributions: 1. Full papers 2. Reviews 3. Papers on Education 4. History of Chemistry 5. Short communications 6. Technical notes 7. Letters to the Editor The Orbital journal also publishes a number of special issues in addition to the regular ones. The central objectives of Orbital are threefold: (i) to provide the general scientific community (at regional, Brazilian, and worldwide levels) with a formal channel for the communication and dissemination of the Chemistry-related literature output by publishing original papers based on solid research and by reporting contributions which further knowledge in the field; (ii) to provide the community with open, free access to the full content of the journal, and (iii) to constitute a valuable channel for the dissemination of Chemistry-related investigations.