Maximilian R. Bailey, Nico Reichholf, Anna Flechsig, F. Grillo, L. Isa
{"title":"一种可扩展的微游泳池合成电流方法","authors":"Maximilian R. Bailey, Nico Reichholf, Anna Flechsig, F. Grillo, L. Isa","doi":"10.33774/chemrxiv-2021-4fmmn","DOIUrl":null,"url":null,"abstract":"Microswimmers are small particles capable of converting available energy sources into propulsion owing to their compositional asymmetry and are promising for applications ranging from targeted delivery to enhanced mixing at the microscale. However, current fabrication techniques demonstrate limited scalability and/or rely on the excessive use of expensive precursor materials. Here, a scalable Pickering-wax emulsion technique is combined with galvanic electrochemistry, to grow platinum films from copper nanoparticles asymmetrically seeded onto SiO\\textsubscript{2} microparticle supports. In this manner, large quantities of Pt-SiO\\textsubscript{2} Janus microswimmers are obtained. Utilising copper as a templating material not only reduces synthesis time, material costs, and toxic waste, but also facilitates the further extension of this methodology to a range of functional materials. This electrochemical approach builds upon previous attempts to overcome the current limitations in microswimmer synthesis and offers exciting opportunities for their future development.","PeriodicalId":72565,"journal":{"name":"ChemRxiv : the preprint server for chemistry","volume":" ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A scalable galvanic approach to microswimmer synthesis\",\"authors\":\"Maximilian R. Bailey, Nico Reichholf, Anna Flechsig, F. Grillo, L. Isa\",\"doi\":\"10.33774/chemrxiv-2021-4fmmn\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Microswimmers are small particles capable of converting available energy sources into propulsion owing to their compositional asymmetry and are promising for applications ranging from targeted delivery to enhanced mixing at the microscale. However, current fabrication techniques demonstrate limited scalability and/or rely on the excessive use of expensive precursor materials. Here, a scalable Pickering-wax emulsion technique is combined with galvanic electrochemistry, to grow platinum films from copper nanoparticles asymmetrically seeded onto SiO\\\\textsubscript{2} microparticle supports. In this manner, large quantities of Pt-SiO\\\\textsubscript{2} Janus microswimmers are obtained. Utilising copper as a templating material not only reduces synthesis time, material costs, and toxic waste, but also facilitates the further extension of this methodology to a range of functional materials. This electrochemical approach builds upon previous attempts to overcome the current limitations in microswimmer synthesis and offers exciting opportunities for their future development.\",\"PeriodicalId\":72565,\"journal\":{\"name\":\"ChemRxiv : the preprint server for chemistry\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-09-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemRxiv : the preprint server for chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.33774/chemrxiv-2021-4fmmn\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemRxiv : the preprint server for chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.33774/chemrxiv-2021-4fmmn","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A scalable galvanic approach to microswimmer synthesis
Microswimmers are small particles capable of converting available energy sources into propulsion owing to their compositional asymmetry and are promising for applications ranging from targeted delivery to enhanced mixing at the microscale. However, current fabrication techniques demonstrate limited scalability and/or rely on the excessive use of expensive precursor materials. Here, a scalable Pickering-wax emulsion technique is combined with galvanic electrochemistry, to grow platinum films from copper nanoparticles asymmetrically seeded onto SiO\textsubscript{2} microparticle supports. In this manner, large quantities of Pt-SiO\textsubscript{2} Janus microswimmers are obtained. Utilising copper as a templating material not only reduces synthesis time, material costs, and toxic waste, but also facilitates the further extension of this methodology to a range of functional materials. This electrochemical approach builds upon previous attempts to overcome the current limitations in microswimmer synthesis and offers exciting opportunities for their future development.