绿色合成颗粒活性炭/锌铁纳米复合材料基生物漂白红土铁(BLaFe),用于吸附-芬顿氧化法去除水中的罗丹明B

IF 1.6 Q3 WATER RESOURCES
B. S, R. K N, Manu B., M. Y. Sreenivasa
{"title":"绿色合成颗粒活性炭/锌铁纳米复合材料基生物漂白红土铁(BLaFe),用于吸附-芬顿氧化法去除水中的罗丹明B","authors":"B. S, R. K N, Manu B., M. Y. Sreenivasa","doi":"10.2166/wpt.2023.014","DOIUrl":null,"url":null,"abstract":"\n Novel cost-effective catalyst granular activated carbon (GAC)-based zinc ferro nanocomposites for the heterogeneous Fenton's oxidation of dye were synthesized using bioleached laterite iron (BLFe) as a precursor and Psidium gujava leaf extract. Synthesized nanocomposites were characterized using SEM, EDS, XRD and BET surface area analysis. The degradation of Rhodamine dye was carried out with nanocomposites using adsorption–Fenton's oxidation process. The catalytic role of nanocomposites in Fenton's oxidation of Rhodamine B (RhB) was investigated and reported. The maximum dye removal of 96.2% was observed with 64.2% COD removal within 200 min of treatment. An increase in nanocomposite dosage has a positive effect on dye removal marking 5 g/L as an optimum dosage. Adsorption studies reveal that RhB removal using BLFe-based GAC/zinc ferro composites fits the Freundlich Adsorption Isotherm model with an adsorption capacity of 47.81 mg/g. A combination of adsorption and Fenton's oxidation has resulted in higher removal efficiency with nanocomposite material. Reusability studies confirm that the spent catalyst can be reused for five cycles.","PeriodicalId":23794,"journal":{"name":"Water Practice and Technology","volume":null,"pages":null},"PeriodicalIF":1.6000,"publicationDate":"2023-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Green synthesis of granular activated carbon/zinc ferro nanocomposites-based bioleached laterite iron (BLaFe) for the removal of Rhodamine B in water using adsorption–Fenton's oxidation process\",\"authors\":\"B. S, R. K N, Manu B., M. Y. Sreenivasa\",\"doi\":\"10.2166/wpt.2023.014\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n Novel cost-effective catalyst granular activated carbon (GAC)-based zinc ferro nanocomposites for the heterogeneous Fenton's oxidation of dye were synthesized using bioleached laterite iron (BLFe) as a precursor and Psidium gujava leaf extract. Synthesized nanocomposites were characterized using SEM, EDS, XRD and BET surface area analysis. The degradation of Rhodamine dye was carried out with nanocomposites using adsorption–Fenton's oxidation process. The catalytic role of nanocomposites in Fenton's oxidation of Rhodamine B (RhB) was investigated and reported. The maximum dye removal of 96.2% was observed with 64.2% COD removal within 200 min of treatment. An increase in nanocomposite dosage has a positive effect on dye removal marking 5 g/L as an optimum dosage. Adsorption studies reveal that RhB removal using BLFe-based GAC/zinc ferro composites fits the Freundlich Adsorption Isotherm model with an adsorption capacity of 47.81 mg/g. A combination of adsorption and Fenton's oxidation has resulted in higher removal efficiency with nanocomposite material. Reusability studies confirm that the spent catalyst can be reused for five cycles.\",\"PeriodicalId\":23794,\"journal\":{\"name\":\"Water Practice and Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2023-02-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Water Practice and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2166/wpt.2023.014\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"WATER RESOURCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water Practice and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2166/wpt.2023.014","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"WATER RESOURCES","Score":null,"Total":0}
引用次数: 1

摘要

以生物浸出的红土铁(BLFe)为前驱体,以番石榴叶提取物为原料,合成了一种用于染料非均相Fenton氧化的新型高效催化剂颗粒活性炭(GAC)基锌铁纳米复合材料。利用SEM、EDS、XRD和BET比表面积分析对合成的纳米复合材料进行了表征。采用吸附-芬顿氧化法,用纳米复合材料对罗丹明染料进行降解。研究并报道了纳米复合材料在芬顿氧化罗丹明B(RhB)中的催化作用。在处理的200分钟内,观察到最大的染料去除率为96.2%,COD去除率为64.2%。纳米复合材料用量的增加对染料去除有积极影响,标记5g/L为最佳用量。吸附研究表明,使用BLFe基GAC/锌铁复合材料去除RhB符合Freundlich吸附等温线模型,吸附容量为47.81mg/g。吸附和芬顿氧化的结合导致纳米复合材料具有更高的去除效率。可重复使用性研究证实,废催化剂可以重复使用五个循环。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Green synthesis of granular activated carbon/zinc ferro nanocomposites-based bioleached laterite iron (BLaFe) for the removal of Rhodamine B in water using adsorption–Fenton's oxidation process
Novel cost-effective catalyst granular activated carbon (GAC)-based zinc ferro nanocomposites for the heterogeneous Fenton's oxidation of dye were synthesized using bioleached laterite iron (BLFe) as a precursor and Psidium gujava leaf extract. Synthesized nanocomposites were characterized using SEM, EDS, XRD and BET surface area analysis. The degradation of Rhodamine dye was carried out with nanocomposites using adsorption–Fenton's oxidation process. The catalytic role of nanocomposites in Fenton's oxidation of Rhodamine B (RhB) was investigated and reported. The maximum dye removal of 96.2% was observed with 64.2% COD removal within 200 min of treatment. An increase in nanocomposite dosage has a positive effect on dye removal marking 5 g/L as an optimum dosage. Adsorption studies reveal that RhB removal using BLFe-based GAC/zinc ferro composites fits the Freundlich Adsorption Isotherm model with an adsorption capacity of 47.81 mg/g. A combination of adsorption and Fenton's oxidation has resulted in higher removal efficiency with nanocomposite material. Reusability studies confirm that the spent catalyst can be reused for five cycles.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
2.30
自引率
6.20%
发文量
136
审稿时长
14 weeks
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信