T. Fan, Jie Zhao, Yingxiang Chen, Miao Wang, Xingming Wang, Shun Wang, Xiaoyang Chen, Akang Lu, Shijiao Zha
{"title":"聚丙烯微塑料对重金属的吸附及共存特性研究","authors":"T. Fan, Jie Zhao, Yingxiang Chen, Miao Wang, Xingming Wang, Shun Wang, Xiaoyang Chen, Akang Lu, Shijiao Zha","doi":"10.1155/2021/4938749","DOIUrl":null,"url":null,"abstract":"Plastic particles with a diameter of 5 mm or less are called microplastics. Microplastics are one of the primary sources of pollution in the environment. It has been proven that microplastics are also carriers of heavy metals, but there are few studies on their adsorption mechanism. In this study, the adsorption of Pb, Cu, Cd, and Zn by polypropylene (PP) microplastics was analyzed and discussed. The morphology of PP was observed by scanning electron microscopy (SEM), the surface elemental composition of PP was determined by X-ray photoelectron spectroscopy (XPS), and the functional groups of PP were analyzed by Fourier transform infrared spectroscopy (FTIR). The results showed that the adsorption behavior of microplastics to different heavy metals could be balanced in 32 hours. Kinetics experiments showed that the adsorption process could be fitted well by a two-stage dynamic model, and the adsorption of Pb and Cu by PP is greater than that of Cd and Zn. The Freundlich model has the best fitting effect on Pb for the adsorption isothermal results. The Langmuir model showed that the process is favorable for adsorption. The adsorption of mixed heavy metals by microplastics showed that when the concentration of the mixed adsorption mass was low, the presence of a coexistence system promoted the adsorption of Zn and Cu by microplastics. With an increasing concentration, the adsorption of 4 heavy metals by microplastics is inhibited.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":" ","pages":""},"PeriodicalIF":2.8000,"publicationDate":"2021-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"16","resultStr":"{\"title\":\"Coexistence and Adsorption Properties of Heavy Metals by Polypropylene Microplastics\",\"authors\":\"T. Fan, Jie Zhao, Yingxiang Chen, Miao Wang, Xingming Wang, Shun Wang, Xiaoyang Chen, Akang Lu, Shijiao Zha\",\"doi\":\"10.1155/2021/4938749\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Plastic particles with a diameter of 5 mm or less are called microplastics. Microplastics are one of the primary sources of pollution in the environment. It has been proven that microplastics are also carriers of heavy metals, but there are few studies on their adsorption mechanism. In this study, the adsorption of Pb, Cu, Cd, and Zn by polypropylene (PP) microplastics was analyzed and discussed. The morphology of PP was observed by scanning electron microscopy (SEM), the surface elemental composition of PP was determined by X-ray photoelectron spectroscopy (XPS), and the functional groups of PP were analyzed by Fourier transform infrared spectroscopy (FTIR). The results showed that the adsorption behavior of microplastics to different heavy metals could be balanced in 32 hours. Kinetics experiments showed that the adsorption process could be fitted well by a two-stage dynamic model, and the adsorption of Pb and Cu by PP is greater than that of Cd and Zn. The Freundlich model has the best fitting effect on Pb for the adsorption isothermal results. The Langmuir model showed that the process is favorable for adsorption. The adsorption of mixed heavy metals by microplastics showed that when the concentration of the mixed adsorption mass was low, the presence of a coexistence system promoted the adsorption of Zn and Cu by microplastics. With an increasing concentration, the adsorption of 4 heavy metals by microplastics is inhibited.\",\"PeriodicalId\":7315,\"journal\":{\"name\":\"Adsorption Science & Technology\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2021-10-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"16\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Adsorption Science & Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1155/2021/4938749\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Adsorption Science & Technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1155/2021/4938749","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Coexistence and Adsorption Properties of Heavy Metals by Polypropylene Microplastics
Plastic particles with a diameter of 5 mm or less are called microplastics. Microplastics are one of the primary sources of pollution in the environment. It has been proven that microplastics are also carriers of heavy metals, but there are few studies on their adsorption mechanism. In this study, the adsorption of Pb, Cu, Cd, and Zn by polypropylene (PP) microplastics was analyzed and discussed. The morphology of PP was observed by scanning electron microscopy (SEM), the surface elemental composition of PP was determined by X-ray photoelectron spectroscopy (XPS), and the functional groups of PP were analyzed by Fourier transform infrared spectroscopy (FTIR). The results showed that the adsorption behavior of microplastics to different heavy metals could be balanced in 32 hours. Kinetics experiments showed that the adsorption process could be fitted well by a two-stage dynamic model, and the adsorption of Pb and Cu by PP is greater than that of Cd and Zn. The Freundlich model has the best fitting effect on Pb for the adsorption isothermal results. The Langmuir model showed that the process is favorable for adsorption. The adsorption of mixed heavy metals by microplastics showed that when the concentration of the mixed adsorption mass was low, the presence of a coexistence system promoted the adsorption of Zn and Cu by microplastics. With an increasing concentration, the adsorption of 4 heavy metals by microplastics is inhibited.
期刊介绍:
Adsorption Science & Technology is a peer-reviewed, open access journal devoted to studies of adsorption and desorption phenomena, which publishes original research papers and critical review articles, with occasional special issues relating to particular topics and symposia.