K. Yoshimura, K. Isobe, Mitsutaka Kawashima, Kyohei Yamaguchi, R. Sok, S. Tokuhara, Jin Kusaka
{"title":"乙醇混合汽油替代燃料火花前放热对发动机燃烧性能的影响","authors":"K. Yoshimura, K. Isobe, Mitsutaka Kawashima, Kyohei Yamaguchi, R. Sok, S. Tokuhara, Jin Kusaka","doi":"10.4271/04-17-01-0003","DOIUrl":null,"url":null,"abstract":"Regulations limiting greenhouse gas (GHG) emissions in the transport sector have\n become more restrictive in recent years, drawing interest to synthetic fuels\n such as e-fuels and biofuels that could “decarbonize” existing vehicles. This\n study focuses on the potential to increase the thermal efficiency of\n spark-ignition (SI) engines using ethanol as a renewable fuel, which requires a\n deep understanding of the effects of ethanol on combustion behavior with high\n compression ratios (CRs). An important phenomenon in this condition is pre-spark\n heat release (PSHR), which occurs in engines with high CRs in boosted conditions\n and changes the fuel reactivity, leading to changes in the burning velocity.\n Fuel blends containing ethanol display high octane sensitivity (OS) and limited\n low-temperature heat release (LTHR). Consequently, their burning velocities with\n PSHR may differ from that of gasoline. This study therefore aimed to clarify the\n effects of ethanol on SI combustion behavior under PSHR conditions. Combustion\n behavior was studied by performing single-cylinder engine experiments and\n chemical kinetics simulations. The experimental measurements were performed to\n characterize the relationship between the occurrence of PSHR and the main\n combustion duration. Analysis of this relationship showed that the\n ethanol-blended fuel has a lesser PSHR and a longer combustion duration than the\n non-ethanol fuel by approximately 5% in high engine load conditions. Simulations\n using input data from the experiments revealed that the ethanol-blended fuel has\n a lower laminar burning velocity due to the lower temperature in the unburned\n mixture caused by its PSHR. Additional simulations examining the chemical effect\n of partially oxidized reactants caused by PSHR on the laminar burning velocity\n showed that partially oxidized reactants increase the laminar burning velocity\n of the ethanol-blended fuel but decrease that of a reference fuel without\n ethanol. A large number of fuel radicals and oxides of the ethanol-blended fuel\n enhances chain-branching reactions in the pre-flame zone and possibly increases\n its laminar burning velocity. However, the thermodynamic effect of PSHR on\n laminar burning velocity exceeds the chemical effect, and thus the\n ethanol-blended fuel has a lower turbulent burning velocity in the PSHR\n conditions.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effects of Pre-spark Heat Release of Ethanol-Blended Gasoline\\n Surrogate Fuels on Engine Combustion Behavior\",\"authors\":\"K. Yoshimura, K. Isobe, Mitsutaka Kawashima, Kyohei Yamaguchi, R. Sok, S. Tokuhara, Jin Kusaka\",\"doi\":\"10.4271/04-17-01-0003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Regulations limiting greenhouse gas (GHG) emissions in the transport sector have\\n become more restrictive in recent years, drawing interest to synthetic fuels\\n such as e-fuels and biofuels that could “decarbonize” existing vehicles. This\\n study focuses on the potential to increase the thermal efficiency of\\n spark-ignition (SI) engines using ethanol as a renewable fuel, which requires a\\n deep understanding of the effects of ethanol on combustion behavior with high\\n compression ratios (CRs). An important phenomenon in this condition is pre-spark\\n heat release (PSHR), which occurs in engines with high CRs in boosted conditions\\n and changes the fuel reactivity, leading to changes in the burning velocity.\\n Fuel blends containing ethanol display high octane sensitivity (OS) and limited\\n low-temperature heat release (LTHR). Consequently, their burning velocities with\\n PSHR may differ from that of gasoline. This study therefore aimed to clarify the\\n effects of ethanol on SI combustion behavior under PSHR conditions. Combustion\\n behavior was studied by performing single-cylinder engine experiments and\\n chemical kinetics simulations. The experimental measurements were performed to\\n characterize the relationship between the occurrence of PSHR and the main\\n combustion duration. Analysis of this relationship showed that the\\n ethanol-blended fuel has a lesser PSHR and a longer combustion duration than the\\n non-ethanol fuel by approximately 5% in high engine load conditions. Simulations\\n using input data from the experiments revealed that the ethanol-blended fuel has\\n a lower laminar burning velocity due to the lower temperature in the unburned\\n mixture caused by its PSHR. Additional simulations examining the chemical effect\\n of partially oxidized reactants caused by PSHR on the laminar burning velocity\\n showed that partially oxidized reactants increase the laminar burning velocity\\n of the ethanol-blended fuel but decrease that of a reference fuel without\\n ethanol. A large number of fuel radicals and oxides of the ethanol-blended fuel\\n enhances chain-branching reactions in the pre-flame zone and possibly increases\\n its laminar burning velocity. However, the thermodynamic effect of PSHR on\\n laminar burning velocity exceeds the chemical effect, and thus the\\n ethanol-blended fuel has a lower turbulent burning velocity in the PSHR\\n conditions.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2023-05-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4271/04-17-01-0003\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4271/04-17-01-0003","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Effects of Pre-spark Heat Release of Ethanol-Blended Gasoline
Surrogate Fuels on Engine Combustion Behavior
Regulations limiting greenhouse gas (GHG) emissions in the transport sector have
become more restrictive in recent years, drawing interest to synthetic fuels
such as e-fuels and biofuels that could “decarbonize” existing vehicles. This
study focuses on the potential to increase the thermal efficiency of
spark-ignition (SI) engines using ethanol as a renewable fuel, which requires a
deep understanding of the effects of ethanol on combustion behavior with high
compression ratios (CRs). An important phenomenon in this condition is pre-spark
heat release (PSHR), which occurs in engines with high CRs in boosted conditions
and changes the fuel reactivity, leading to changes in the burning velocity.
Fuel blends containing ethanol display high octane sensitivity (OS) and limited
low-temperature heat release (LTHR). Consequently, their burning velocities with
PSHR may differ from that of gasoline. This study therefore aimed to clarify the
effects of ethanol on SI combustion behavior under PSHR conditions. Combustion
behavior was studied by performing single-cylinder engine experiments and
chemical kinetics simulations. The experimental measurements were performed to
characterize the relationship between the occurrence of PSHR and the main
combustion duration. Analysis of this relationship showed that the
ethanol-blended fuel has a lesser PSHR and a longer combustion duration than the
non-ethanol fuel by approximately 5% in high engine load conditions. Simulations
using input data from the experiments revealed that the ethanol-blended fuel has
a lower laminar burning velocity due to the lower temperature in the unburned
mixture caused by its PSHR. Additional simulations examining the chemical effect
of partially oxidized reactants caused by PSHR on the laminar burning velocity
showed that partially oxidized reactants increase the laminar burning velocity
of the ethanol-blended fuel but decrease that of a reference fuel without
ethanol. A large number of fuel radicals and oxides of the ethanol-blended fuel
enhances chain-branching reactions in the pre-flame zone and possibly increases
its laminar burning velocity. However, the thermodynamic effect of PSHR on
laminar burning velocity exceeds the chemical effect, and thus the
ethanol-blended fuel has a lower turbulent burning velocity in the PSHR
conditions.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.