几种恶唑酮类分子在1N H2SO4溶液中作为API5LX60钢缓蚀剂的研究

Q1 Earth and Planetary Sciences
Parijat Burhagohain , Gitalee Sharma , Prankush Malla Bujarbaruah
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引用次数: 2

摘要

在API5LX60钢输送管道频繁使用的石油行业,腐蚀被认为是一个值得注意的问题。在本报告中,研究了三种恶唑酮衍生物作为潜在的缓蚀剂,在浓度为50-200 ppm的1N H2SO4溶液中,在停滞条件下对API5LX60级碳钢进行了腐蚀研究。对测试样品进行的失重和电阻腐蚀监测技术显示,在200 ppm的抑制剂浓度下,抑制性能最好。结果进一步表明,抑制程度呈浓度依赖性。在200 ppm浓度下,抑制剂I的抑制率最高,为90.70%。采用多元线性回归模型进行统计分析,得到R2高值0.998,p值<0.0001表明抑制剂效率与恶唑酮浓度和钢的重量损失呈平滑的线性关系。再次,表面分析证实了缓蚀剂在钢表面形成了保护涂层。此外,恶唑酮类缓蚀剂在钢表面的物理吸附服从Langmuir等温线,线性相关系数为0.9992。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of a few oxazolone molecules as corrosion inhibitor for API5LX60 steel in 1N H2SO4 solution

Corrosion is recognized as a notable problem in oil sector where API5LX60 steel transmission pipelines are in frequent use. In this report, three oxazolone derivatives as potential corrosion inhibitors were investigated on API5LX60 graded carbon steel in 1N H2SO4 solution in stagnant conditions at concentrations 50–200 ppm. Gravimetric weight loss coupons and electrical resistance corrosion monitoring techniques performed on test samples showed inhibitory properties with best at 200 ppm inhibitor concentration. The results further revealed that the degree of inhibition was concentration dependent. Inhibitor I exhibited the highest inhibition efficiency of 90.70% at 200 ppm concentration. Statistical analysis using multiple linear regression model procreated high R2 value of 0.998 and p-value < 0.0001 asserting a smooth linear dependence of inhibitor efficiency on oxazolone concentration and weight loss of the steel. Again, surface analysis affirmed the formation of protective coating of inhibitor on steel surface. Furthermore, the oxazolone inhibitor adsorbed physically on the steel surface and obeyed the Langmuir isotherm which is evident from the linear correlation coefficient value of 0.9992.

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来源期刊
Egyptian Journal of Petroleum
Egyptian Journal of Petroleum Earth and Planetary Sciences-Geochemistry and Petrology
CiteScore
7.70
自引率
0.00%
发文量
29
审稿时长
84 days
期刊介绍: Egyptian Journal of Petroleum is addressed to the fields of crude oil, natural gas, energy and related subjects. Its objective is to serve as a forum for research and development covering the following areas: • Sedimentation and petroleum exploration. • Production. • Analysis and testing. • Chemistry and technology of petroleum and natural gas. • Refining and processing. • Catalysis. • Applications and petrochemicals. It also publishes original research papers and reviews in areas relating to synthetic fuels and lubricants - pollution - corrosion - alternate sources of energy - gasification, liquefaction and geology of coal - tar sands and oil shale - biomass as a source of renewable energy. To meet with these requirements the Egyptian Journal of Petroleum welcomes manuscripts and review papers reporting on the state-of-the-art in the aforementioned topics. The Egyptian Journal of Petroleum is also willing to publish the proceedings of petroleum and energy related conferences in a single volume form.
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