Cheon Hyeon Cho, Karam Han, C. Sohn, Jeong-sik Han
{"title":"层流反应器丙烯反应的实验研究及其还原机理的验证","authors":"Cheon Hyeon Cho, Karam Han, C. Sohn, Jeong-sik Han","doi":"10.15231/jksc.2019.24.3.009","DOIUrl":null,"url":null,"abstract":"Flow reactors are classified into laminar flow, turbulent flow and jet-stirred reactors depending on flow condition. Laminar flow reactor is a device that measures oxidation process of gaseous fuel and vaporized liquid fuels. Propene oxidation process was observed in a laminar flow reactor with a specified residence time at 6 atm, 968 K, and equivalence ratio of 0.71 and compared with numerical simulations. The Aramco 2.0 chemistry was adopted as a kinetic mechanism which includes 493 species and about 2,700 reaction steps. Oxygen, carbon monoxide, and carbon dioxide concentrations were measured. Numerical results with a time shift of 0.216 s show a good agreement with experimental results. And, a reduced kinetic mechanism was generated and validated based on the Aramco 2.0. The reaction steps are reduced by 23%.","PeriodicalId":42247,"journal":{"name":"Journal of the Korean Society of Combustion","volume":" ","pages":""},"PeriodicalIF":0.7000,"publicationDate":"2019-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"An Experimental Study of Propene Reaction of a Laminar Flow Reactor and Validation of its Reduced Mechanism\",\"authors\":\"Cheon Hyeon Cho, Karam Han, C. Sohn, Jeong-sik Han\",\"doi\":\"10.15231/jksc.2019.24.3.009\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Flow reactors are classified into laminar flow, turbulent flow and jet-stirred reactors depending on flow condition. Laminar flow reactor is a device that measures oxidation process of gaseous fuel and vaporized liquid fuels. Propene oxidation process was observed in a laminar flow reactor with a specified residence time at 6 atm, 968 K, and equivalence ratio of 0.71 and compared with numerical simulations. The Aramco 2.0 chemistry was adopted as a kinetic mechanism which includes 493 species and about 2,700 reaction steps. Oxygen, carbon monoxide, and carbon dioxide concentrations were measured. Numerical results with a time shift of 0.216 s show a good agreement with experimental results. And, a reduced kinetic mechanism was generated and validated based on the Aramco 2.0. The reaction steps are reduced by 23%.\",\"PeriodicalId\":42247,\"journal\":{\"name\":\"Journal of the Korean Society of Combustion\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2019-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Korean Society of Combustion\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15231/jksc.2019.24.3.009\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENGINEERING, MECHANICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Korean Society of Combustion","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15231/jksc.2019.24.3.009","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, MECHANICAL","Score":null,"Total":0}
An Experimental Study of Propene Reaction of a Laminar Flow Reactor and Validation of its Reduced Mechanism
Flow reactors are classified into laminar flow, turbulent flow and jet-stirred reactors depending on flow condition. Laminar flow reactor is a device that measures oxidation process of gaseous fuel and vaporized liquid fuels. Propene oxidation process was observed in a laminar flow reactor with a specified residence time at 6 atm, 968 K, and equivalence ratio of 0.71 and compared with numerical simulations. The Aramco 2.0 chemistry was adopted as a kinetic mechanism which includes 493 species and about 2,700 reaction steps. Oxygen, carbon monoxide, and carbon dioxide concentrations were measured. Numerical results with a time shift of 0.216 s show a good agreement with experimental results. And, a reduced kinetic mechanism was generated and validated based on the Aramco 2.0. The reaction steps are reduced by 23%.