腐殖物质对Bushveld杂岩铬铁矿中PGE风化的影响:风化环境的实验模拟

IF 1.2 4区 地球科学 Q2 GEOLOGY
E. Kotzé, S. Schuth, S. Goldmann, F. Holtz
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引用次数: 0

摘要

有机酸,包括腐植酸,在含有Pt和Pd等金属的矿物的风化中起着重要作用。它们也在新的湿法冶金方法中被考虑用于释放非常规PGE矿石的反应物之列(如津巴布韦Great Dyke的氧化矿石,以及南非Bushveld复合体中含PGE层暴露于风化的地点)。为了更好地了解Bushveld杂岩中含pge铬铁矿的风化过程,对来自南非某铬矿的铬铁矿精矿与不同浓度的合成腐植酸进行了反应。结果证实钯在环境中的迁移率比铂高。粉碎后的铬铁矿精矿与未粉碎的精矿相比,Cr的流动性较大,而Pd和Pt的流动性较小。随着腐植酸浓度的增加,溶液中Pd和Pt的含量增加。这些实验对布什维尔德复合体中铬铁矿的风化过程有了深入的了解。主要含Pd、pt矿物不在铬铁矿内,而是在晶界处赋存。因此,它们可以通过铬铁矿的分解和沿铬铁矿晶界渗透的水来释放。一旦在溶液中,Pd比Pt更具流动性,并进一步分散。有机酸在风化过程中起着重要的作用,因为它们能够增强PGE,特别是Pd的流动性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The influence of humic substances on the weathering of PGE in chromitite of the Bushveld Complex: An experimental simulation of the weathering environment
Organic acids, including humic acid, play a significant role in the weathering of minerals containing metals such as Pt and Pd. They are also among the reactants which are under consideration for new hydrometallurgical methods of liberating unconventional PGE ores (such as the oxidised ores of the Great Dyke, Zimbabwe, and at locations in the Bushveld Complex of South Africa where PGE-bearing layers have been exposed to weathering). In order to better understand the processes operating during weathering of PGE-bearing chromitite seams of the Bushveld Complex, chromite concentrate originating from a South African chromium mine was subjected to reaction with different concentrations of synthetic humic acid. The results confirm the greater mobility of palladium in the environment compared to platinum. Crushed chromite concentrate showed greater mobility of Cr, but not of Pd or Pt, compared to uncrushed concentrate. Increasing the concentration of humic acid increased the amount of Pd and Pt in solution. These experiments give insight into the processes that govern the weathering of chromitite in the Bushveld Complex. The main Pd– and Pt-bearing minerals are not enclosed within chromite but occur at grain boundaries. Thus, they can be liberated by disaggregation of chromite and infiltration of water along chromite grain boundaries. Once in solution, Pd is more mobile than Pt and is dispersed further. Organic acids play an important role during the weathering process as they are capable of enhancing the mobility of the PGE, particularly Pd.
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来源期刊
CiteScore
3.60
自引率
5.60%
发文量
18
审稿时长
>12 weeks
期刊介绍: The South African Journal of Geology publishes scientific papers, notes, stratigraphic descriptions and discussions in the broadly defined fields of geoscience that are related directly or indirectly to the geology of Africa. Contributions relevant to former supercontinental entities such as Gondwana and Rodinia are also welcome as are topical studies on any geoscience-related discipline. Review papers are welcome as long as they represent original, new syntheses. Special issues are also encouraged but terms for these must be negotiated with the Editors.
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