铜-磷酸化合物意外的C-O键裂解

IF 0.6 Q4 CHEMISTRY, ORGANIC

Molbank Pub Date : 2023-06-05 DOI:10.3390/m1659

Steven G Dannenberg, R. Waterman

引用次数: 0

摘要

在IPrCuPPh2与丙烯酸甲酯的反应中意外地形成了甲醇铜化合物IPrCuOMe。从反应混合物中鉴定出醇盐产物，并对其进行了结构表征。这种C–O键断裂反应可能取决于IPrCuPPh2的Cu–P键的亲核性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Unexpected C–O Bond Cleavage by a Copper–Phosphido Compound

Copper methoxide compound IPrCuOMe was unexpectedly formed in a reaction of IPrCuPPh2 with methyl acrylate. The alkoxide product was identified from the reaction mixture spectroscopically and structurally characterized. This C–O bond cleavage reaction likely depends on nucleophilicity of the Cu–P bond of IPrCuPPh2.

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来源期刊

Molbank Chemistry-Physical and Theoretical Chemistry

CiteScore

0.70

自引率

33.30%

发文量

174

审稿时长

11 weeks

期刊介绍： •organic synthesis •biosynthesis •extraction and purification •natural product derivatives •structural elucidation (X-ray crystallography, NMR, etc.)